Synthesis of Cu^II-Nanocrystal Coordination Polymer by Microemulsion Method. Straightforward Experiment of Nanomaterial Synthesis for Science High School Students

Kiattipoom Rodpun^1,

¹Department of Chemistry, Mahidol Wittayanusorn School (MWITS), Salaya, Nakorn Pathom, 73170, Thailand

Cite this paper:
Kiattipoom Rodpun. Synthesis of Cu^II-Nanocrystal Coordination Polymer by Microemulsion Method. Straightforward Experiment of Nanomaterial Synthesis for Science High School Students. World Journal of Chemical Education. 2017; 5(3):107-111. doi: 10.12691/wjce-5-3-5

Abstract

This work aims to demonstrate the experiment which was applied in the academic recreation club at science high school for learning about coordination chemistry and nanomaterial synthesis. Accordingly, the synthesis of the nanocrystal coordination polymer (NCP) by microemulsion method was employed as an example for this purpose. In this work, the general microemulsion (µEm) method was modified in order to provide the straightforward procedure for the synthesis of Cu^II-NCP for high school students. The results from transmission electron microscopy (TEM) and infrared spectroscopy (IR) were also discussed with the students.

Keywords:
nanocrystal coordination polymer microemulsion method nanomaterial synthesis science high school students

This work is licensed under a Creative Commons Attribution 4.0 International License. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/

References:

[1]	Rodpun, K.; Lucas, N.T.; Tan, E. W.; Meledandri, C. J. Development of solvent- dispersible coordination polymer nanocrystals and application as efficient heterogeneous catalysts. CrystGrowthDes 2016, 16, 3940-3946.
[2]	Leong, W. L.; Vittal, J. J., One-dimensional coordination polymers: complexity and diversity in structures, properties, and applications. Chem. Rev. 2010, 111, 688-764.
[3]	Robin, A. Y.; Fromm, K. M., Coordination polymer networks with O- and N-donors: What they are, why and how they are made. Coord. Chem. Rev. 2006, 250, 2127-2157.
[4]	Carne, A.; Carbonell, C.; Imaz, I.; Maspoch, D., Nanoscale metal-organic materials. Chem. Soc. Rev. 2011, 40, 291-305.
[5]	Zhang, X.; Ballem, M. A.; Ahrén, M.; Suska, A.; Bergman, P.; Uvdal, K., Nanoscale Ln(III)-carboxylate coordination polymers (Ln = Gd, Eu, Yb): temperature-controlled guest encapsulation and light harvesting. J. Am. Chem. Soc. 2010, 132, 10391-10397.
[6]	Yin, Y.; Alivisatos, A. P., Colloidal nanocrystal synthesis and the organic-inorganic interface. Nature 2005, 437, 664-670.
[7]	Arora, H.; Lloret, F.; Mukherjee, R., One-dimensional coordination polymers of MnII, CuII, and ZnII supported by carboxylate-appended (2-pyridyl)alkylamine ligands – structure and magnetism. Eur. J. Inorg. Chem. 2009, 3317-3325.
[8]	Arora, H.; Mukherjee, R., Coordination polymers using (2-pyridyl)alkylamine-appended carboxylates: magnetic properties. New J. Chem. 2010, 34, 2357-2365.
[9]	Rodpun, K.; Blackman, A. G.; Gardiner, M. G.; Tan, E. W.; Meledandri, C. J.; Lucas, N.T. Alkyl linker effects on the coordination topology of ditopic di(2-pyridylmethyl)amine carboxylate ligands with ZnII and CuII: polymers vs. macrocycles. CrystEngComm 2015, 17, 2974-2988.
[10]	Yin, Y.; Alivisatos, A. P. Nature 2005, 437, 664-670.
[11]	Ganguli, A. K.; Ganguly, A.; Vaidya, S., Microemulsion-based synthesis of nanocrystalline materials. Chem. Soc. Rev. 2010, 39, 474-485.
[12]	Garden, A. L.; van der Salm, L.; Schwass, D. R.; Meledandri, C. J., Towards a tunable microemulsion method for nanoparticle synthesis. RSC Adv. 2013, 3, 2192-2196.
[13]	Nakamoto, K., Infrared Spectra of Inorganic and Coordination Compounds. John Wiley & Sons, Inc.: 2009.
[14]	Socrates, G., Infared and Raman Characteristic Group Frequencies. John Wiley & Sons Ltd: 2001.