World Journal of Chemical Education
ISSN (Print): 2375-1665 ISSN (Online): 2375-1657 Website: https://www.sciepub.com/journal/wjce Editor-in-chief: Prof. V. Jagannadham
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World Journal of Chemical Education. 2025, 13(1), 7-16
DOI: 10.12691/wjce-13-1-2
Open AccessArticle

Analysis of p-Nitrophenol Reduction

Achim Habekost1,

1University of Education Ludwigsburg, Germany

Pub. Date: February 11, 2025

Cite this paper:
Achim Habekost. Analysis of p-Nitrophenol Reduction. World Journal of Chemical Education. 2025; 13(1):7-16. doi: 10.12691/wjce-13-1-2

Abstract

p-Nitrophenol (p-Np) is a chemical compound that causes various problems in the environment. The main aspects of the environmental problem are : Toxicity to humans, animals and aquatic organisms and persistence in the environment. p-Np is a relatively stable compound and therefore degrades slowly in the environment (up to years in anaerobic environments). Through industrial effluents and pesticide applications (e.g. degradation products of parathion) it can accumulate in ecosystems and become a long-term problem. Due to its solubility in water, p-Np can easily penetrate groundwater and endanger drinking water supplies. Modern waste water treatment with appropriate measures is therefore necessary. Purification methods such as adsorption, photocatalysis and electrochemical oxidation are used to eliminate p-Np in wastewater . Their monitoring helps to identify the sources of pollution, to safeguard water quality and thus to protect the health of ecosystems and people in the long term. In particular, electrochemical and spectroscopic methods have been developed for the detection and quantification of p-Np . This article presents two analytical methods for the identification of p-Np: UV-VIS and Raman spectroscopy. The combination with electrochemical methods such as linear sweep voltammetry (LSV) and differential pulse voltammetry (DPV) allows the spectroscopic monitoring of the redox reactions of p-Np.

Keywords:
Reduction of p-Nitrophenol UV-VIS spectroscopy SERS-Raman spectroscopy

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References:

[1]  Tchieno F.M.M., Tonle I.K. P-Nitrophenol determination and remediation: an overview, Rev. Anal. Chem. 2018, 37/2, 1.
 
[2]  Houcini H., Laghrib L., Bakasse M., Lahrich S., El Mhammedi M.A. Catalytic activity of gold for the electrochemical reduction of p-nitrophenol: analytical application. Int. J. Environ. Anal. Chem. 2019, 100/14, 1.
 
[3]  Liu S., Qileng A., Huang J., Gao Q., Liu Y. Polydopamine as a bridge to decorate monodisperse gold nanoparticles on Fe3O4 nanoclusters for the catalytic reduction of 4-nitrophenol, RCS Adv, 2017, 7, 45545.
 
[4]  Mendez D., Vargas R., Borras C., Blanco S., Mostany J., Scharifker B.R. A rotating disk study of the photocatalytic oxidation of p-nitrophenol on phosphorus-modified TiO2 photocatalyst, Appl. Catal. B: Environmental, 2015, 166-167, 529.
 
[5]  Vargas R, Borras C., Plana D., Mostany J., Scharifker B.R, Electrochemical oxygen transfer reactions: electrode materials, surface processes, kinetic models, linear free energy correlations, and perspectives, Electrochim. Act. 2010, 55, 6501.
 
[6]  Emmanuel N., Nair R.B, Abraham B., Karuvath Y., Fabricating a Low-Cost Raman Spectrometer to Introduce Students to Spectroscopy Basics and Applied Instrument Design, J. Chem. Educ. 2021, 98, 2109−2116.
 
[7]  Bard A.J., Faulkner L.R., Electrochemical Methods. Fundamentals and Applications, 2nd Edition, 2001, John Wiley, Hoboken, NY.
 
[8]  Ashraf, S., Ur-Rehman S., Sher F., Khalid Z.M., Mehmood M., Hussain I., Synthesis of cellulose-metal nanoparticle composites: Development and comparison of different protocols, Cellulose, 2014, 21, 395.
 
[9]  Zhang H., Zhou K., Ye T., Xu H., Xie, M., Sun P., Dong X., Reduction of p-Nitrophenol with Modified Coal Fly Ash Supported by Palladium Catalysts, Catalyst, 2024, 14, 600.
 
[10]  Muniz-Miranda M., SERS monitoring of the catalytic reduction of 4-nitrophenol on Ag-doped titania nanoparticles, Appl. Catal. B: Environmental, 2014, 146, 147.
 
[11]  Krishna R., Fernandes D.M., Dias C., Ventura J., Ramana E.V., Freire C., Titus E., Facile synthesis of Co/RGO nanocomposite for methylene blue dye removal, Int. J. Hydr. Ener. 2015, 40, 4996.
 
[12]  Lee P.C., Meisel D., J. Phys. Chem. 1982, 86, 3391.
 
[13]  DeBleye C., Dumont E., Rozet E., Sacre P.Y., Chavez P.F., Netchacovitch L., Piel G., Hubert P., Ziemons E., Determination of 4-aminophenol in a pharmaceutical formulation using surface enhanced Raman scattering: from development to method validation, Talanta, 2013, 116, 899.
 
[14]  Martin-Yerga D., Perez-Junquera A., Gonzalez-Garcia M.B., Perales-Rondon J.V., Heras A., Colina A., Hernandez-Santos D., Fanjul-Bolado P., Quantitative Raman spectroelectrochemistry using silver screen-printed electrodes, Electrochim. Act. 2018, 264.
 
[15]  McCall J., Richter M.M., Phenol substituent effects on electrogenerated chemiluminescence quenching, Analyst, 2000, 125, 545.
 
[16]  Jackson W., Bobbitt D.R., Chemiluminescence detection of amino acids using in situ generation Ru(bpy)33+, Anal. Chim. Acta, 1994, 285, 309.
 
[17]  Brune S.N., Bobbitt D.R., Role of electron-donating/withdrawing character, pH, and stoichiometry on the chemiluminescent reaction of tris(2,2'-bipyridine)ruthenium(II) with amino acids, Anal. Chem. 1992, 64, 166.
 
[18]  Miao W., Electrogenerated chemiluminescence and its biorelated applications, Chem. Rev. 2008, 108, 2506-2553.