Spectroelectrochemistry with Low-cost Instruments

A. Habekost^1,

¹University of Education Ludwigsburg, Ludwigsburg, Germany

Cite this paper:
A. Habekost. Spectroelectrochemistry with Low-cost Instruments. World Journal of Chemical Education. 2023; 11(4):149-156. doi: 10.12691/wjce-11-4-4

Abstract

Processes at electrodes can be monitored simultaneously electrochemically and spectroscopically. In electrochemical science, expensive equipment is needed to study these spectroelectrochemical processes. Because of the high price of these instruments, they are often not used in university education. Several experiments of three chemiluminescence systems with low-cost instruments are presented and partly compared with the expensive setups

Keywords:
electrogenerated chemiluminescence low-cost spectroelectrochemistry

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References:

[1]	W.R. Heineman, Spectroelectrochemistry. J. Chem. Educ. 1983, 60, (4). 305-308.
[2]	W. Miao, J.P. Choi, A.J. Bard, ElectrogeneratedChemiluminescence 69: The Tris(2,2'-bipyridine)ruthenium(II), (Ru(bpy)32+)/Tri-n-propylamine (TPrA) System Revisited - A New Route Involving TPrA •+ Cation Radicals, J. Am. Chem. Soc. 2002, 124, 14478.
[3]	A. Kapturkiewicz, Electrogenerated chemiluminescence from the tris(2,2'-bipyridine)ruthenium(II) complex, Chem. Phys. Lett. 1995, 236, 389.
[4]	D. M. Hercules, F. E. Lytle, Chemiluminescence from reduction reactions, J. Am. Chem. Soc. 1966, 88, 4795.
[5]	M. M. Richter, Electrochemiluminescence (ECL), Chem. Rev. 2004, 104, 30.
[6]	A. Habekost, Spectroscopic and Electrochemical Investigations of N-(Phosphonomethyl)glycine and (Aminomethyl)phosphonic Acid (AMPA), World J. Chem. Educ. 3 (2015) 134-140.
[7]	D. Ibanez, M.B. Gonzalez-Garcia, D. Hernandez-Santos, P. Fanjul-Bolado, Understanding the ECL interaction of luminol and [Ru(bpy)3]2+ luminophores by spectroelectrochemiluminescence, Phys. Chem. Chem. Phys. 2020, 22, 18261.
[8]	O. V. Reshetnyak, z, E. P. Kovalchuk, and J. Blajejowski, Role of Molecular Oxygen and Its Active Forms in Generation of Electrochemiluminescence, Rus. J. of Electrochem., 2011, 47, 10, 1111–1118.
[9]	M.M.P.S. Neves, M.B. Gonzales-Garcia, D. Hernandez-Santos, P. Fanjul-Bolado, A Miniturized Flow Injection Analysis System for Electrogenerated Chemiluminescence-Based Assays, ChemElectroChem, 2017, 4, 1686-1689.