American Journal of Environmental Protection
ISSN (Print): 2328-7241 ISSN (Online): 2328-7233 Website: https://www.sciepub.com/journal/env Editor-in-chief: Mohsen Saeedi, Hyo Choi
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American Journal of Environmental Protection. 2023, 11(1), 7-14
DOI: 10.12691/env-11-1-2
Open AccessArticle

Investigation of Nigerian Coconut Shell and Banana Peels for the Removal of Carbon Monoxide (CO) in Indoor Environment

T.O. Ogunjinmi1, , O.F. Ogayemi2, F. A. Akeredolu1 and J. A. Sonibare1

1Department of Chemical Engineering, Obafemi Awolowo University, Ile-Ife, Osun State, Nigeria

2Institute for Sustainable Development, First Technical University Ibadan, Oyo State, Nigeria

Pub. Date: March 06, 2023

Cite this paper:
T.O. Ogunjinmi, O.F. Ogayemi, F. A. Akeredolu and J. A. Sonibare. Investigation of Nigerian Coconut Shell and Banana Peels for the Removal of Carbon Monoxide (CO) in Indoor Environment. American Journal of Environmental Protection. 2023; 11(1):7-14. doi: 10.12691/env-11-1-2

Abstract

In this study, copper chloride modified activated carbon was synthesised by thermal monolayer dispersion (deposition) process. Characterization of the adsorbents were carried out using Fourier Transform Infrared Spectroscopy (FTIR), proximate analysis and ultimate analysis. Furthermore, Response Surface Methodology (RSM) and Artificial Neural Network (ANN) were combined to determine the optimum conditions at which the synthesised adsorbent can remove carbon monoxide from the ambient environment. It cost implication was also determined. This was with a view to examine the Carbon Monoxide removal potential of the synthesised adsorbent. The characterization results showed that the prepared activated carbon are suitable precursor for the impregnation of copper (I) chloride. The RSM showed the optimum condition to be 20g CuCl/CSAC for 10mins with predicted CO adsorption of 77.01% with R2 value of 0.9843 and 15g of CuCl/BPAC for 10mins with predicted CO adsorption of 69.71% with R2 value of 0.9759. The ANN results were 25g CuCl/CSAC for 10mins with predicted CO adsorption of 77.15% with R2 value of 1 and 20g of CuCl/BPAC for 10mins with predicted CO adsorption of 69.17% with R2 value of 1. The ANN model indicates a better accuracy over RSM.

Keywords:
adsorption carbon monoxide RSM and ANN

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References:

[1]  West, J. J., Cohen, A., Dentener, F., Brunekreef, B., Zhu, T., Armstrong, B., Bell, M., Brauer, M, Carmichael, G. R., Costa, D., Dockery, D., Kleeman, M. J., Krzyzanowski, M, Kunzli, N., Liousse, C., Lung, S. C, Martin, R. V., Pöschl, U., Pope, C. A., Roberts, J. M., Russell, A. G., and Wiedinmyer, C. (2016). “What We Breathe Impacts Our Health: Improving Understanding of the Link between Air Pollution and Health.” Environmental Science & Technology, 50 (10), 4895-4904.
 
[2]  W.H.O, (2014). Public Health, Environmental and Social Determinants of Health (PHE). http://www.who.int/phe/health_topics/outdoorair/databases, Accessed date: 31 May 2018.
 
[3]  Lan, L., Wargocki, P., Wyon, D. P., and Lian, Z. (2011). Effects of thermal discomfort in an office on perceived air quality, SBS symptoms, physiological responses, and human performance. Indoor Air. 21 (5) 376-390.
 
[4]  Li, T., Cao, S., Fan, D., Zhang, Y., Wang, B., Zhao X., Leaderer, B.P., Shen, G., Zhang, Y., and Duan, X. (2016). Household concentrations and personal exposure of PM 2.5 among urban residents using different cooking fuels, Sci. Total Environ. 5, 548-549.
 
[5]  Langston, J. W., Widner, H., and Brooks, D. (2010). Carbon Monoxide Poisoning. Encyclopedia of Movement Disorder, 1,187.
 
[6]  Zhong, K., Yang, F., and Kang, Y. M. (2013). Indoor and outdoor relationships of CO concentrations in natural ventilating rooms in summer, Shanghai. Building and Environment. 62, 69-76.
 
[7]  W.H.O, (2010). Guidelines for Indoor Air Quality: Selected Pollutants. http://www.euro.who.int/__data/assets/pdf_file/0009/128169/e94535.pdf, Accessed date: 31 May 2018.
 
[8]  Chalouka, A., and Mayroidis, I. (2002). Comparison of Indoor and Outdoor Concentration of CO at a Public School. Evaluation of an indoor air quality model. Atmospheric Environments, 1769-1781.
 
[9]  Reboul, C., Thireau, J., Meyer, G., Andre, L., Obert, P., Cazorla, O., and Richard S. (2012). Carbon Monoxide Exposure in the Urban Environment: An Insidious Foe for the Heart. Respiratory Physiology and Neurobiology, 184(2), 204-212.
 
[10]  DeCoste, J.B.; Peterson, G.W (2014). Metal–organic frameworks for air purification of toxic chemicals. Chem. Rev, 114, 5695-5727
 
[11]  Auta, M., and Hameed, B. H. (2013). Coalesced chitosan activated carbon composite for batch and fixed-bed adsorption of cationic and anionic dyes. Colloids and Surfaces B: Biointerfaces. 105, 199-206.
 
[12]  Gopinath, A., and Kadirvelu, K. (2018). Strategies to design modified activated carbon fibers for the decontamination of water and air. Environ Chem Let,t 16,1137-1168.
 
[13]  Morin-Crini, N., Loiacono, S., Placet, V., Torri, G., Bradu, C., Kostić, M., Cosentino, C., Chanet, G., Martel, B., and Lichtfouse, E. (2019). Hemp-based adsorbents for sequestration of metals: a review. Environ Chem Lett 17 (1) 393-408.
 
[14]  Wang, L., Zhao, J., Yan, T., Sun, Y. Y., and Zhang S. B. (2011). Titanium-decorated graphene oxide for carbon monoxide capture and separation, Physical Chemistry Chemical Physics, 13, 21126-21131.
 
[15]  Lopes, F. V. S., Grande, C. A., Ribeiro, A. M., Loureiro, J. M., Evaggelos, O., Nikolakis, V., and Rodrigues, A. E., (2009). Adsorption of H2, CO2, CH4, CO, N2 and H2O in Activated Carbon and Zeolite for Hydrogen Production. Separation Science and Technology 44, 1045-1073.
 
[16]  Delgado, J. A., Gueda, V. I. A., Uguina, M. A., Sotelo, J. L., Brea, P., and Grande, C. A. (2014). Adsorption and diffusion of H2, CO, CH4 and CO2 in BPL activated carbon and 13X zeolite: Evaluation of performance in pressure swing adsorption hydrogen purification by simulation, Ind. Eng. Chem. Res. 53, 15414-15426.
 
[17]  Tsutaya, H., and lzumi J. (1991). Carbon monoxide adsorption by Zeolite, Zeolites, 11, 90.
 
[18]  Sethia, G., Somani, R. S., and Chand-Bajaj, H. (2015). Adsorption of carbon monoxide, methane and nitrogen on alkaline earth metal ion exchanged Zeolite-X: structure, cation position and adsorption relationship. RSC Adv, 5, 12773-12781.
 
[19]  Munusamy, K., Sethia, G., Patil, D. V., Somayajulu-Rallapalli, P. B., Somani, R. S. and Bajaj, H. (2012). Sorption of carbon dioxide, methane, nitrogen and carbon monoxide on MIL-101(Cr): volumetric measurements and dynamic adsorption studies. Chemical Engineering Journal, 6, 359-368.
 
[20]  Agueda, V. I., Delgado, J. A., Uguina, M. A., Brea, P., Spjelkavik, A. I., Blom, R., and Grande C. (2015). Adsorption and diffusion of H2, N2, CO, CH4 and CO2 in UTSA-16 metal-organic framework extrudates. Chemical Engineering Science, 124, 159-169.
 
[21]  Cheng, L. S., and Yang R. T. (1995). Monolayer cuprous chloride dispersed on pillared clays for olefin-paraffin separations by π-complexation. Adsorption, 1(1) 61-75.
 
[22]  Grande, C. A., Araujo, J. D. P., Cavenati, S., Firpo, N., Basaldella, E., and Rodrigues, A. E. (2004). New π-complexation Adsorbents for Propane-propylene separation. Langmuir, 20(13), 5291-5297.
 
[23]  Hirai, H., Wada, K., and Komiyama, M. (1986). Active Carbon-Supported Copper (1) Chloride as Solid Adsorbent for Carbon Monoxide. Bull Chemical Society of Japan, 59: 2217-2223.
 
[24]  Golden, T. C., Kratz, W. C., Wilhelm, F. C., Pierantozzi, R., and Rokicki, A. (1992). Highly dispersed cuprous compositions. US. Pat., 5,137-175.
 
[25]  Tamon, H., Kitamura, K., and Okazaki, M. (1996). Adsorption of Carbon Monoxide on Activated Carbon Impregnated with Metal Halide. Analytical Chemistry Journal, 42 (2) 422-430.
 
[26]  Xie, Y., Zhang, J., Qiu, J., Tong, X., Fu, J., Yang, G., Yan, H., and Tang Y. (1997). Zeolites modified by CuCl for separating CO from gas mixtures containing CO2, Adsorption, 3, 27-32.
 
[27]  Peng, J., Xian, S., Xiao, J., Huang, Y., Xia, Q., Wang, H., and Li, Z. (2015). A Supported Cu (I)/ MIL-100 (Fe) adsorbent with high CO adsorption capacity and CO/N2 selectivity. Chemical Engineering Journal, 270, 282-289.
 
[28]  Yang, R. T. (2003). Adsorbents: Fundamentals and applications, John Wiley & Sons, New Jersey, 2003, 1(10) 54-79.
 
[29]  King, C. J., (1987). Handbook of Separation Process Technology, ed. R. W. Rousseau, Wiley, New York.
 
[30]  Guo, S., Peng, J., Li, W., Yang, W., Zhang, L., Zhang, S., and Xia, H. (2009). Effects of CO2 activation on porous structures of coconut shell-based activated carbons. Applied Surface Science 255, 8443-8449.
 
[31]  Viena, V., Elvitriana, and Wardani S. (2018). Application of banana peels waste as adsorbents for the removal of CO2, NO, NOx, and SO2 gases from motorcycle emissions. Materials Science and Engineering 334, 1-9.
 
[32]  Gao F., Wang Y., Wang X., Wang S., (2016). Selective CO adsorbent CuCl/AC prepared using CuCl2 as a precursor by a facile method. RSC Adv. 6:34439–34446.
 
[33]  American Society for Testing and Material (2009). Standard Terminology of Coal and Coke, ASTM D121-09a.1, 1-14.
 
[34]  Jabit, N. B. (2007). The Production and Characterization of Activated Carbon Using Local Agricultural Waste through Chemical Activation Process, Thesis submitted in fulfilments of the requirements for the degree of Master of Science.
 
[35]  Aziza, A., Odiakosa, A., Nwajei, G., and Orodu, V. (2008). Modification and Characterization of Activated Carbon Derived from Sawdust. Conference Proceeding, CSN Delta Chem. 235-243
 
[36]  Malik, R., Ramteke, D., and Water, S. (2006). Physico-chemical and surface characterization of adsorbent prepared from groundnut shell by ZnCl2 activation and its ability to adsorb colour. Indian Journal of Chemical Technology. 13, 329-333.
 
[37]  Olowoyo, D. N., and Orere, E. E. (2012). Preparation and characterization of A.C. made from Palm kernel shell, coconut shell, groundnut shell and Obechi wood. Investigation of apparent density, total ash content, moisture contents and particle size distribution. International Journal of Research in Chemistry and Environment. 2 (3) 32-35.
 
[38]  Kumar, A., and Jena, H. M. (2015). High surface area microporous activated carbons prepared from Fox nut (Euryale ferox) shell by zinc chloride activation. Applied Surface Science, 356, 753-761.