Applied Ecology and Environmental Sciences
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Applied Ecology and Environmental Sciences. 2025, 13(1), 34-43
DOI: 10.12691/aees-13-1-5
Open AccessArticle

Hydrochemical Assessment of Groundwater Quality from Fractured Basement Aquifers in the South-central of Burkina Faso, West Africa

Césard Millogo1, 2, , Aboubakar Sako1, 2, Blehiman Sagnon3 and Samuel Nakolendoussé2

1UFR/Sciences Appliquées et Technologies, Université Daniel OUEZZIN COULIBALY, BP 139, Dédougou, Burkina Faso

2Laboratoire Géosciences et Environnement (LaGE), Département des Sciences de la Terre, Université Joseph KI-ZERBO, Ouagadougou, Burkina Faso

3Bureau des Mines et de la Géologie du Burkina (BUMIGEB), 01 B.P 601 Ouagadougou 01, Burkina Faso

Pub. Date: May 07, 2025

Cite this paper:
Césard Millogo, Aboubakar Sako, Blehiman Sagnon and Samuel Nakolendoussé. Hydrochemical Assessment of Groundwater Quality from Fractured Basement Aquifers in the South-central of Burkina Faso, West Africa. Applied Ecology and Environmental Sciences. 2025; 13(1):34-43. doi: 10.12691/aees-13-1-5

Abstract

In central southern Burkina Faso, as elsewhere in the country, groundwater resources are the reliable source of drinking water. During its residence time in the rocks, the groundwater interacts with them and its chemical composition is considerably modified. Methods like major ions geochemistry, the assessment of water quality indices, and the application of geostatistical analysis have been utilized to define the hydrogeochemical processes governing groundwater quality. For this study, 249 groundwater samples were taken from manual boreholes. The findings indicated that the groundwaters ranged from circumneutral to alkaline, with predominant concentrations of Ca2+, Mg2+ and HCO3-. According to the calculated groundwater quality indices, water from the majority of the boreholes was suitable for domestic uses. However, a few boreholes had high concentrations of F- and FeT that exceeded the World Health Organization recommended guideline value for drinking water. The elevated F- concentrations were probably due to the weathering of the granitic rocks, while the FeT concentrations appeared to come from the water pumps installed on these boreholes. Bivariate plots indicated that geochemical processes like silicate weathering, mineral dissolution and precipitation, ion exchange, and evapotranspiration were the key factors affecting solute acquisition in groundwater. Furthermore, desorption and ion exchange in alkaline pH conditions could enhance F⁻ enrichment in groundwater. Zones with low ionic strength and electrical conductivity have been identified as groundwater recharge zones, which should be protected and subject to a regular monitoring program. This study results could help professionals in the field to implement appropriate groundwater quality management strategies.

Keywords:
fractured basement aquifers spatial assessment groundwater hydrochemical evolution kriging Burkina Faso

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References:

[1]  C. Grimaldi, ‘Grimaldi C. Hydrochimie de petits bassins versants Apports à la connaissance du fonctionnement géochimique du sol et de la qualité de l’eau des cours d’eau,’ in : UMR INRA-Agrocampus « Sol Agronomie Spatialisation » Rennes, Université de Rennes 1, 2004.
 
[2]  S. G. Johnston, E. D. Burton, T. Aaso, and G. Tuckerman, ‘Sulfur, iron and carbon cycling following hydrological restoration of acidic freshwater wetlands’, Chem. Geol., vol. 371, pp. 9–26, 2014.
 
[3]  W. Liu and J. B. Sha, ‘Failure mode transition of Nb phase from cleavage to dimple/tear in Nb-16Si-based alloys prepared via spark plasma sintering’, Mater. Des., vol. 111, pp. 301–311, Dec. 2016.
 
[4]  C. Neukum and R. Azzam, ‘Impact of climate change on groundwater recharge in a small catchment in the Black Forest, Germany’, Hydrogeol. J., vol. 20, pp. 547–560, 2012.
 
[5]  R. R. Pant et al., ‘Spatiotemporal variations of hydrogeochemistry and its controlling factors in the Gandaki River Basin, Central Himalaya Nepal’, Sci. Total Environ., vol. 622–623, pp. 770–782, May 2018.
 
[6]  K. W. Mandernack, L. Lynch, H. R. Krouse, and M. D. Morgan, ‘Sulfur cycling in wetland peat of the New Jersey Pinelands and its effect on stream water chemistry’, Geochim. Cosmochim. Acta, vol. 64, pp. 3949–3964, 2000.
 
[7]  G. L. Macpherson, ‘CO2 distribution in groundwater and the impact of groundwater extraction on the global C cycle’, Chem. Geol., vol. 264, pp. 328–336, 2009.
 
[8]  J. I. Drever, The Geochemistry of Natural Waters: Surface and Groundwater Environments. Prentice Hall, 1997. [Online]. Available: https:// books.google.bf/ books?id=mbYPAQAAIAAJ.
 
[9]  H. P. Broers and B. van der Grift, ‘Regional monitoring of temporal changes in groundwater quality’, J. Hydrol., vol. 296, no. 1, pp. 192–220, 2004.
 
[10]  M. Jalali and Z. V. Khanlari, ‘Major ion chemistry of groundwaters in the Damagh area, Hamadan, western Iran’, Environ. Geol., vol. 54, no. 1, pp. 87–93, Mar. 2008.
 
[11]  J. Perrin, S. Ahmed, and D. Hunkeler, ‘The effects of geological heterogeneities and piezometric fluctuations on groundwater flow and chemistry in a hard-rock aquifer, southern India’, Hydrogeol. J., vol. 19, pp. 1189–1201, 2011.
 
[12]  C. Millogo, C. Bakouan, and S. Sawadogo, ‘Caractérisation physico-chimique des eaux de surface et des altérites du bassin versant du lac Bam, Centre Nord du Burkina Faso’, Afr. Sci., vol. 5, no. 17, pp. 137–150, 2020.
 
[13]  C. Millogo, C. Bakouan, A. Sako, and S. Nakolendoussé, ‘Hydrogeochemical Characterization and Multivariate Analysis of Groundwater in Pala, Burkina Faso: Implications for Sustainable Water Management’, Int. Res. J. Pure Appl. Chem., vol. 25, no. 5, pp. 17–34, Aug. 2024.
 
[14]  G. B. Bonan, ‘Effects of Land Use on the Climate of the United States’, Clim. Change, vol. 37, no. 3, pp. 449–486, Nov. 1997.
 
[15]  R. A. Pielke et al., ‘Interactions between the atmosphere and terrestrial ecosystems: influence on weather and climate’, Glob. Change Biol., vol. 4, 1998, [Online]. Available: https:// api.semanticscholar.org/ CorpusID: 85591113.
 
[16]  A. J. Pitman, G. T. Narisma, R. A. Pielke, and N. J. Holbrook, ‘Impact of land cover change on the climate of southwest Western Australia’, J. Geophys. Res. Atmospheres, vol. 109, no. D18, p. 2003JD004347, Sep. 2004.
 
[17]  R. F. Stallard and J. M. Edmond, ‘Geochemistry of the Amazon: 2. The influence of geology and weathering environment on the dissolved load’, J. Geophys. Res., vol. 88, pp. 9671–9688, 1983.
 
[18]  A. K. Singh, B. Raj, A. K. Tiwari, and M. K. Mahato, ‘Evaluation of hydrogeochemical processes and groundwater quality in the Jhansi district of Bundelkhand region, India’, Environ. Earth Sci., vol. 70, pp. 1225–1247, 2013.
 
[19]  A. Kundu and S. K. Nag, ‘Assessment of groundwater quality in Kashipur Block, Purulia district, West Bengal’, Appl. Water Sci., vol. 8, pp. 1–18, 2018.
 
[20]  C. Bolm, ‘A new iron age’. Macmillan Publishers Limited, 2009.
 
[21]  S. Swain, A. K. Taloor, L. Dhal, S. Sahoo, and N. Al-Ansari, ‘Impact of climate change on groundwater hydrology: a comprehensive review and current status of the Indian hydrogeology’, Appl. Water Sci., vol. 12, no. 6, p. 120, Jun. 2022.
 
[22]  D. Ityel, ‘Ground water: Dealing with iron contamination’, Filtr. Sep., vol. 48, no. 1, pp. 26–28, Jan. 2011.
 
[23]  R. Thapa, S. Gupta, H. Kaur, and S. Rajak, ‘Search for potential iron contamination zones in Burdwan district: an approach through fuzzy logic’, Sustain. Water Resour. Manag., vol. 5, no. 3, pp. 1017–1031, Sep. 2019.
 
[24]  G. W. Israel, ‘Evaluation and comparison of three atmospheric fluoride monitors under field conditions’, Atmospheric Environ. 1967, vol. 8, no. 2, pp. 159–166, Feb. 1974.
 
[25]  J. Polomski, H. Flühler, and P. Blaser, ‘Accumulation of Airborne Fluoride in Soils 1’, J. Environ. Qual., vol. 11, pp. 457–461, 1982.
 
[26]  N. P. Gritsan and G. W. Miller, ‘Correlation among heavy metals and fluoride in soil, air and plants in relation to environmental damage’, 2009. [Online]. Available: https:// api. semanticscholar.org/ CorpusID: 34665415.
 
[27]  Y. Sun et al., ‘Assessment of potential toxicological risk for public health of heavy metal iron in diverse wheat varieties irrigated with various types of waste water in South Asian country’, Agric. Water Manag., vol. 276, p. 108044, Feb. 2023.
 
[28]  WHO, ‘Guidelines for drinking-water quality’, 2011, Accessed: Aug. 10, 2024. [Online]. Available: https:// iris.who.int/ handle/10665/44584.
 
[29]  USGS, ‘Drinking Water Taste and Odor’. Accessed: Aug. 01, 2024. [Online]. Available: https://www.usgs.gov/mission-areas/water-resources/science/drinking-water-taste-and-odor.
 
[30]  Gouvernement du Québec, ‘Principaux contaminants de l’eau potable d’un puits’. Accessed: Jul. 15, 2024. [Online]. Available: https://www.quebec.ca/agriculture-environnement-et-ressources-naturelles/eau-potable/contamination-eau-potable-puits/contaminants-eau-puits/fer.
 
[31]  G. C. Ghosh, Md. J. H. Khan, T. K. Chakraborty, S. Zaman, A. H. M. E. Kabir, and H. Tanaka, ‘Human health risk assessment of elevated and variable iron and manganese intake with arsenic-safe groundwater in Jashore, Bangladesh’, Sci. Rep., vol. 10, no. 1, p. 5206, Mar. 2020.
 
[32]  K. W. F. Howard, ‘Sustainable cities and the groundwater governance challenge’, Environ. Earth Sci., vol. 73, no. 6, pp. 2543–2554, Mar. 2015.
 
[33]  M. R. Khan et al., ‘Megacity pumping and preferential flow threaten groundwater quality’, Nat. Commun., vol. 7, 2016, [Online]. Available: https:// api.semanticscholar.org/ CorpusID:12331258.
 
[34]  C. Millogo, B. Sagnon, S. Kafando, and S. Nakolendoussé, ‘Hydrochemical Assessment of Groundwater Quality in the City of Manga and the Surrounding Area, Burkina Faso, West Africa’, Am. J. Water Resour., vol. 12, no. 4, pp. 139–148, Nov. 2024.
 
[35]  P. Debels, R. Figueroa, R. Urrutia, R. Barra, and X. Niell, ‘Evaluation of Water Quality in the Chillán River (Central Chile) Using Physicochemical Parameters and a Modified Water Quality Index’, Environ. Monit. Assess., vol. 110, no. 1–3, pp. 301–322, Nov. 2005.
 
[36]  M. V. Prasanna et al., ‘Identification of the geochemical processes in coastal groundwater using hydrogeochemical and isotopic data: A Case study of the Gadilam river basin in southern India’, 2008. [Online]. Available: https:// api.semanticscholar.org/ CorpusID: 134483767.
 
[37]  S. Chidambaram et al., ‘Significance of pCO2 values in determining carbonate chemistry in groundwater of Pondicherry region, India’, Front. Earth Sci., vol. 5, no. 2, pp. 197–206, 2011.
 
[38]  W. Ocampo-Duque, M. Schuhmacher, and J. L. Domingo, ‘A neural-fuzzy approach to classify the ecological status in surface waters’, Environ. Pollut., vol. 148, no. 2, pp. 634–641, Jul. 2007.
 
[39]  H. Boyacıoğlu, ‘Development of a water quality index based on a European classification scheme’, Water SA, vol. 33, pp. 101–106, 2009.
 
[40]  DGMB, ‘Carte de la migration des isohyètes au cours de 1951à 2000.’, Ouagadougou, Burkina Faso, 2010.
 
[41]  N. Kagambega and C. Castaing, ‘Notice explicative de la Carte géologique du Burkina Faso à 1/200 000 ; Feuille NC-30-XXIII Pô’, BRGM, Orléans – France, N° 7.ACP.BK.074, 2003.
 
[42]  N. Kagambega, ‘Typologie des granitoïdes Paléoprotérozoïque (Birimien) du Burkina Faso - Afrique de l’ouest : Approche pétrologique dans la région de Pô’, Université Cheikh Anta Diop de Dakar, Dakar, Sénégal, 2005.
 
[43]  P. A. Domenico and F. W. Schwartz, ‘Physical and Chemical Hydrogeology.’ Wiley, 1990.
 
[44]  C. R. Ramakrishnaiah, C. Sadashivaiah, and G. Ranganna, ‘Assessment of Water Quality Index for the Groundwater in Tumkur Taluk, Karnataka State, India’, J. Chem., vol. 6, no. 2, pp. 523–530, Jan. 2009.
 
[45]  M. Ketata-Rokbani, M. Gueddari, and R. Bouhlila, ‘Use of Geographical Information System and Water Quality Index to Assess Groundwater Quality in El Khairat Deep Aquifer (Enfidha, Tunisian Sahel)’, 2011. [Online]. Available: https:// api.semanticscholar.org/ CorpusID: 91176792.
 
[46]  M. Coetsiers and K. Walraevens, ‘Chemical characterization of the Neogene Aquifer, Belgium’, Hydrogeol. J., vol. 14, no. 8, pp. 1556–1568, Nov. 2006.
 
[47]  D. A. Lipson et al., ‘Water-table height and microtopography control biogeochemical cycling in an Arctic coastal tundra ecosystem’, Biogeosciences, vol. 9, pp. 577–591, 2011.
 
[48]  M. O. Rivett, J. W. N. Smith, S. R. Buss, and P. Morgan, ‘Nitrate occurrence and attenuation in the major aquifers of England and Wales’, Q. J. Eng. Geol. Hydrogeol., vol. 40, no. 4, pp. 335–352, 2007.
 
[49]  E. Petelet-Giraud, P. Négrel, L. Gourcy, C. Schmidt, and M. Schirmer, ‘Geochemical and isotopic constraints on groundwater-surface water interactions in a highly anthropized site. The Wolfen/Bitterfeld megasite (Mulde subcatchment, Germany).’, Environ. Pollut., vol. 148 3, pp. 707–17, 2007.
 
[50]  R. A. Freeze and J. A. Cherry, Groundwater. Englewood Cliffs, N.J: Prentice-Hall, 1979.
 
[51]  J. D. Hem, ‘Calculation and Use of Ion Activity’, p. 25, 1961.
 
[52]  C. N. Sawyer, P. L. McCarty, and G. F. Parkin, ‘Chemistry for environmental engineering and science’, 2002. [Online]. Available: https://api.semanticscholar.org/CorpusID:109456116
 
[53]  Y. Srinivasa Rao and D. K. Jugran, ‘Delineation of groundwater potential zones and zones of groundwater quality suitable for domestic purposes using remote sensing and GIS’, Hydrol. Sci. J., vol. 48, no. 5, pp. 821–833, Oct. 2003.
 
[54]  H. A. Schroeder, ‘Relations between hardness of water and death rates from certain chronic and degenerative diseases in the United States.’, J. Chronic Dis., vol. 12, pp. 586–591, Dec. 1960.
 
[55]  J. Wu et al., ‘Spatiotemporal variation of groundwater quality in an arid area experiencing long-term paper wastewater irrigation, northwest China’, Environ. Earth Sci., vol. 76, no. 13, p. 460, Jul. 2017.
 
[56]  S. Rose, ‘Comparative major ion geochemistry of Piedmont streams in the Atlanta, Georgia region: possible effects of urbanization’, Environ. Geol., vol. 42, no. 1, pp. 102–113, May 2002.
 
[57]  K. M. Subrahmanyam and P. Yadaiah, ‘Assessment of the impact of industrial effluents on water quality in Patancheru and environs, Medak district, Andhra Pradesh, India’, Hydrogeol. J., vol. 9, pp. 297–312, 2001.
 
[58]  E. K. Berner and R. A. Berner, ‘Global Water Cycle: Geochemistry and Environment’, 1987. [Online]. Available: https://api.semanticscholar.org/CorpusID:128967808
 
[59]  T. H. E. Heaton, ‘Sources of the nitrate in phreatic groundwater in the western Kalahari’, J. Hydrol., vol. 67, pp. 249–259, 1984.
 
[60]  C. A. J. Appelo and D. Postma, Geochemistry, groundwater and pollution, CRC Press. London, 2005.
 
[61]  J. N. Aranibar, I. C. Anderson, S. Ringrose, and S. A. Macko, ‘Title: Importance of nitrogen fixation in soil crusts of southern African arid ecosystems: acetylene reduction and stable isotope studies’, J. Arid Environ., vol. 54, pp. 345–358, 2003.
 
[62]  T. H. E. Heaton, A. S. Talma, and J. C. Vogel, ‘Origin and history of nitrate in confined groundwater in the western Kalahari’, J. Hydrol., vol. 62, pp. 243–262, 1983.
 
[63]  J. M. Holloway and R. A. Dahlgren, ‘Nitrogen in rock: Occurrences and biogeochemical implications’, Glob. Biogeochem. Cycles, vol. 16, no. 4, Dec. 2002.
 
[64]  P. Li, J. Wu, and H. Qian, ‘Hydrochemical appraisal of groundwater quality for drinking and irrigation purposes and the major influencing factors: a case study in and around Hua County, China’, Arab. J. Geosci., vol. 9, no. 1, p. 15, Dec. 2015.
 
[65]  R. J. Billings, R. J. Berkowitz, and G. Watson, ‘Teeth’, Pediatrics, vol. 113, no. 4 Suppl, p. 1120—1127, Apr. 2004.
 
[66]  P. Kharb and A. K. Susheela, ‘Fluoride ingestion in excess and its effect on organic and certain inorganic constituents of soft tissues’, Med. Sci. Res., vol. 22, pp. 43–44, 1994.
 
[67]  T. D. Mackay and W. M. Thomson, ‘Enamel defects and dental caries among Southland children’, N. Z. Dent. J., vol. 101, no. 2, p. 35—43, Jun. 2005.
 
[68]  W. B. Apambire, D. R. Boyle, and F. A. Michel, ‘Geochemistry, genesis, and health implications of fluoriferous groundwaters in the upper regions of Ghana’, Environ. Geol., vol. 33, no. 1, pp. 13–24, Dec. 1997.
 
[69]  M. G. Edmunds and P. L. Smedley, ‘Fluoride in Natural Waters’, 2013. [Online]. Available: https:// api.semanticscholar.org/ CorpusID: 53344015.
 
[70]  J. Wu and Z. Sun, ‘Evaluation of Shallow Groundwater Contamination and Associated Human Health Risk in an Alluvial Plain Impacted by Agricultural and Industrial Activities, Mid-west China’, Expo. Health, vol. 8, no. 3, pp. 311–329, Sep. 2016.
 
[71]  J. A. Barth, ‘Das Vorkommen der chemischen Elemente auf der Erde’, 1935. [Online]. Available: https:// api.semanticscholar.org/ CorpusID: 129103469.
 
[72]  J. Gaillardet, B. Dupré, P. Louvat, and C. J. Allègre, ‘Global silicate weathering and CO2 consumption rates deduced from the chemistry of large rivers’, Chem. Geol., vol. 159, no. 1, pp. 3–30, 1999.
 
[73]  A. K. Tiwari, R. Ghione, M. De Maio, and M. Lavy, ‘Evaluation of hydrogeochemical processes and groundwater quality for suitability of drinking and irrigation purposes: a case study in the Aosta Valley region, Italy’, Arab. J. Geosci., vol. 10, no. 12, p. 264, Jun. 2017.
 
[74]  M. Meybeck, ‘Global chemical weathering of surficial rocks estimated from river dissolved loads’, Am. J. Sci., vol. 287, pp. 401–428, 1987.
 
[75]  T. E. Cerling, B. L. Pederson, and K. L. V. Damm, ‘Sodium-calcium ion exchange in the weathering of shales: Implications for global weathering budgets’, Geology, vol. 17, pp. 552–554, 1989.
 
[76]  R. S. Fisher and I. William F. Mullican, ‘Hydrochemical Evolution of Sodium-Sulfate and Sodium-Chloride Groundwater Beneath the Northern Chihuahuan Desert, Trans-Pecos, Texas, USA’, Hydrogeol. J., vol. 5, pp. 4–16, 1997.
 
[77]  J. Jankowski and R. Acworth, ‘Impact of Debris-Flow Deposits on Hydrogeochemical Processes and the Developement of Dryland Salinity in the Yass River Catchment, New South Wales, Australia’, Hydrogeol. J., vol. 5, pp. 71–88, 1997.
 
[78]  R. Barzegar, A. A. Moghaddam, M. Najib, N. Kazemian, and J. F. Adamowski, ‘Characterization of hydrogeologic properties of the Tabriz plain multilayer aquifer system, NW Iran’, Arab. J. Geosci., vol. 9, pp. 1–17, 2016.
 
[79]  M. H. Ozler, ‘Hydrochemistry and salt-water intrusion in the Van aquifer, east Turkey’, Environ. Geol., vol. 43, no. 7, pp. 759–775, Mar. 2003.