Applied Ecology and Environmental Sciences
ISSN (Print): 2328-3912 ISSN (Online): 2328-3920 Website: https://www.sciepub.com/journal/aees Editor-in-chief: Alejandro González Medina
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Applied Ecology and Environmental Sciences. 2021, 9(3), 356-367
DOI: 10.12691/aees-9-3-6
Open AccessArticle

Preparation and Characterization of Clay/Urea Formaldehyde Resin Composites

Swati Kalra1, and G.P. Singh1

1Department of Physics, Govt. Dungar College, Bikaner 334001 Rajasthan, India

Pub. Date: March 22, 2021

Cite this paper:
Swati Kalra and G.P. Singh. Preparation and Characterization of Clay/Urea Formaldehyde Resin Composites. Applied Ecology and Environmental Sciences. 2021; 9(3):356-367. doi: 10.12691/aees-9-3-6

Abstract

Composites of urea-formaldehyde/clay were synthesized and analyzed in the present study. The analyses of XRD, FTIR, DSC, and TGA were performed to investigate the variation of urea-formaldehyde (UF)/clay composites' structural and thermal properties with different clay loading levels. It was discovered that the clay loading level influences the glass transition temperature of UF resin. Thermo Gravimetric Analysis (TGA) has shown that the degree of clay loading and heating rate affects the composites' thermal stability. Furthermore, the curing reactions' activation energy was investigated using Kissinger's and Ozawa's methods, confirming the presence of interactions between the polymer chain and clay particles.

Keywords:
clay urea-formaldehyde composites FTIR XRD TGA DSC

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References:

[1]  S Pavlidou and CD Papaspyrides. “A review on polymer–layered silicate nanocomposites”. In: Progress in polymer science 33.12 (2008), pp. 1119-1198.
 
[2]  Lei Wang et al. “Preparation, morphology and thermal/mechanical properties of epoxy/nanoclay composite”. In: Composites Part A: applied science and manufacturing 37.11 (2006), pp. 1890-1896.
 
[3]  Amit Das et al. “Rubber–clay nanocomposites: some recent results”. In: Advanced rubber composites. Springer, 2010, pp. 85-166.
 
[4]  Natacha Bitinis et al. “Recent advances in clay/polymer nanocomposites”. In: Advanced Materials 23.44 (2011), pp. 5229-5236.
 
[5]  S Saengsuwan and S Saikrasun. “Thermal stability of styrene–(ethylene butylene)–styrene­ based elastomer composites modified by liquid crystalline polymer, clay, and carbon nanotube”. In: Journal of thermal analysis and calorimetry 110.3 (2012), pp. 1395-1406.
 
[6]  Zuzana Dujkova, Dagmar Merinska, and Miroslav Slouf. “Fire retardation of polystyrene/clay nanocomposites: Initial study on synergy effect”. In: Journal of Thermoplastic Composite Materials 26.9 (2013), pp. 1278-1286.
 
[7]  Hasmukh A Patel et al. “Nanoclays for polymer nanocomposites, paints, inks, greases and cosmetics formulations, drug delivery vehicle and waste water treatment”. In: Bulletin of Materials Science 29.2 (2006), pp. 133-145.
 
[8]  David Chu, Quang Nguyen, and Donald G Baird. “Effect of matrix molecular weight on the dispersion of nanoclay in unmodified high density polyethylene”. In: Polymer composites 28.4 (2007), pp. 499-511.
 
[9]  Quang T Nguyen and Donald G Baird. “An improved technique for exfoliating and dispersing nanoclay particles into polymer matrices using supercritical carbon dioxide”. In: Polymer 48.23 (2007), pp. 6923-6933.
 
[10]  Suprakas Sinha Ray and Masami Okamoto. “Polymer/layered silicate nanocomposites: a review from preparation to processing”. In: Progress in polymer science 28.11 (2003), pp. 1539-1641.
 
[11]  Baljinder K Kandola et al. “Effect of different compatibilisers on nanoclay dispersion, thermal stability, and burning behavior of polypropylene–nanoclay blends”. In: Journal of applied polymer science 108.2 (2008), pp. 816-824.
 
[12]  Alfred Tcherbi­Narteh et al. “Thermal stability and degradation of di glycidyl ether of bisphenol A epoxy modified with different nanoclays exposed to UV radiation”. In: Polymer degradation and stability 98.3 (2013), pp. 759-770.
 
[13]  K Natarajan and KS Anu. “Nanoclay Reinforced polyurethane­epoxy blend: a review”. In: Int. J. Res. Eng. Adv. Technol 3.1 (2015), pp. 78-90.
 
[14]  S Martı́nez Stagnaro, Cristina Volzone, and L Huck. “Nanoclay as adsorbent: evaluation for removing dyes used in the textile industry”. In: Procedia Materials Science 8 (2015), pp. 586-591.
 
[15]  Ashraf EM Khater et al. “Natural radionuclides in clay deposits: concentration and dose assessment”. In: Radiation protection dosimetry 156.3 (2013), pp. 321-330.
 
[16]  MF Mota et al. “Organophilic clay for oil/water separation process by finite bath tests”. In: Brazilian journal of petroleum and gas 5.2 (2011).
 
[17]  R Suresh et al. “Nanoclay drug delivery system”. In: International Journal of Pharmaceutical Sciences and Nanotechnology 3.2 (2010), pp. 901-905.
 
[18]  Arimitsu Usuki et al. “Swelling behavior of montmorillonite cation exchanged for ω­amino acids by Journal of Materials Research 8.5 (1993), pp. 1174-1178.
 
[19]  Dimitris Bikiaris, Vassilis Karavelidis, and George Karayannidis. “A new approach to pre­ pare poly (ethylene terephthalate)/silica nanocomposites with increased molecular weight and fully adjustable branching or crosslinking by SSP”. In: Macromolecular Rapid Communications 27.15 (2006), pp. 1199-1205.
 
[20]  E Roumeli et al. “Synthesis, characterization and thermal analysis of urea–formaldehyde/nanoSiO2 resins”. In: Thermochimica Acta 527 (2012), pp. 33-39.
 
[21]  Sivananda S Jada. “The structure of urea—formaldehyde resins”. In: Journal of applied polymer science 35.6 (1988), pp. 1573-1592.
 
[22]  Suzana Samaržija­Jovanović et al. “Thermal behavior of modified urea–formaldehyde resins”. In: Journal of thermal analysis and calorimetry 104.3 (2011), pp. 1159-1166.
 
[23]  Nilgün Kızılcan and Mehmet Mermutlu. “In situ preparation of cyclohexanone formaldehyde resin/layered silicate nanocomposites”. In: Journal of Applied Polymer Science 131.6 (2014).
 
[24]  Esin Ateş, Nurseli Uyanık, and Nilgün Kızılcan. “Preparation of urea formaldehyde resin/layered silicate nanocomposites”. In: Pigment & Resin Technology (2013).
 
[25]  Ming Liu et al. “Characterization of the crystalline regions of cured urea formaldehyde resin”. In: RSC advances 7.78 (2017), pp. 49536-49541.
 
[26]  Brian C Smith. Infrared spectral interpretation: a systematic approach. CRC press, 1998.
 
[27]  BS Mamatha. “Studies on nanoclay based multi particle layered biocomposite”.
 
[28]  Qiaojia Lin et al. “Property of nano­SiO 2/urea formaldehyde resin”. In: Frontiers of Forestry in China 1.2 (2006), p. 230.
 
[29]  Ahmet Gürses et al. “Investigation of Thermal Properties of PUF/colored Organoclay Nanocomposites”. In: Acta Physica Polonica A 4.127 (2015), pp. 979-983.
 
[30]  Rhutesh K Shah and Donald R Paul. “Organoclay degradation in melt processed polyethylene nanocomposites”. In: Polymer 47.11 (2006), pp. 4075-4084.
 
[31]  Emiko Otsuka et al. “Effects of microcrystallites on swelling behavior in chemically crosslinked poly (vinyl alcohol) gels”. In: Journal of Polymer Science Part B: Polymer Physics 49.2 (2011), pp. 96-102.
 
[32]  EE Ferg, A Pizzi, and DC Levendis. “13C NMR analysis method for urea–formaldehyde resin strength and formaldehyde emission”. In: Journal of Applied Polymer Science 50.5 (1993), pp. 907-915.
 
[33]  A Despres and A Pizzi. “Colloidal aggregation of aminoplastic polycondensation resins: Urea– formaldehyde versus melamine-formaldehyde and melamine–urea–formaldehyde resins”. In: Journal of applied polymer science 100.2 (2006), pp. 1406-1412.
 
[34]  Henry Kuo Feng Cheng et al. “Thermal kinetics of montmorillonite nanoclay/maleic anhydride­ modified polypropylene nanocomposites”. In: Journal of thermal analysis and calorimetry 109.1 (2012), pp. 17-25.
 
[35]  John Cuppoletti. Nanocomposites and polymers with analytical methods. BoD–Books on Demand, 2011.
 
[36]  Fouad Laoutid et al. “New prospects in flame retardant polymer materials: from fundamentals to nanocomposites”. In: Materials Science and Engineering: R: Reports 63.3 (2009), pp. 100-125.
 
[37]  Kazumasa Matusita, Takayuki Komatsu, and Ryosuke Yokota. “Kinetics of non­isothermal crystallization process and activation energy for crystal growth in amorphous materials”. In: Journal of Materials Science 19.1 (1984), pp. 291-296.
 
[38]  Roger L Blaine and Homer E Kissinger. “Homer Kissinger and the Kissinger equation”. In: Thermochimica acta 540 (2012), pp. 1-6.
 
[39]  K Ozawa. “Estimating isothermal life from thermogravimetric data”. In: Bull Chem Soc Jpn 38 (1966), pp. 1881-4.
 
[40]  A Manzur and F Hernández­Sánchez. “Activation energy for the glass transition of a confined elastomer in HDPE/PP blends”. In: Journal of Macromolecular Science, Part B: Physics 45.1 (2006), pp. 139-152.
 
[41]  Junling Yuan, Xiaowen Zhao, and Lin Ye. “Structure and properties of urea­formaldehyde resin/polyurethane blend prepared via in­situ polymerization”. In: RSC Adv.