eng Science and Education Publishing World Journal of Chemical Education 2375-1657 2023-12-10 11 4 141 148 10.12691/wjce-11-4-3 WJCE20231143 article Surusch Djalali 1 2 Amitabh Banerji 3 Martin Kleinschmidt 4 Peter Gilch gilch@hhu.de, lena.halbruegge@hhu.de 4 Lena Halbr¨¹gge gilch@hhu.de, lena.halbruegge@hhu.de 4 5 Institut f¨¹r Physikalische Chemie, Heinrich-Heine-Universit?t D¨¹sseldorf, Universit?tsstr. 1, 40225 D¨¹sseldorf, Germany Institut f¨¹r Chemiedidaktik, Universit?t Potsdam, Didaktik der Chemie, Karl-Liebknecht-Str. 24-25, 14476 Potsdam, Germany Institut f¨¹r Theoretische Chemie und Computerchemie, Heinrich-Heine-Universit?t D¨¹sseldorf, Universit?tsstr. 1, 40225 D¨¹sseldorf, Germany Atoms and molecules with two unpaired electrons can adopt singlet and triplet spin multiplicities. The implications of this are far reaching. For instance, the properties of molecular oxygen with its triplet ground state cannot be understood if this is not considered. In the design of emitters for OLEDs, the energy gap between singlet and triplet excitations is of utmost importance. This energy gap equals twice the exchange energy. Because of this relevance, the exchange energy is treated in textbooks and courses on physical and quantum chemistry. The treatments are commonly based on the quantum mechanical formalism and leave the students wondering why the exchange energy is non-zero. Here, the formalism is briefly re-iterated. Then wavefunctions for singlet and triplet states with identical configurations are visualized relying on the well-known particle-in-a-box model. The visualization shows that in the triplet state the electrons ¡°automatically¡± avoid each other. This lowers the triplet energy compared to the singlet one. Some short comings of this didactic approach are also discussed. https://pubs.sciepub.com/wjce/11/4/3/wjce-11-4-3.pdf upper-division undergraduate chemistry bachelor programs in Europe physical chemistry quantum chemistry photochemistry exchange energy particle-in-a-box model