1Institute for Organic Chemistry, Bulgarian Academy of Science, Acad. G. Bonchev Street, Building 9, 1113 Sofia
2Managing director “NITIAT” Ltd, Sofia, Bulgaria
3University of Ruse “Angel Kanchev”, 8003 Ruse, Bulgaria
4University of Chemical Technology and Metallurgy, 1756 Sofia, Bulgaria
Chemical Engineering and Science.
2015,
Vol. 3 No. 1, 1-6
DOI: 10.12691/ces-3-1-1
Copyright © 2015 Science and Education PublishingCite this paper: Z. Glavcheva-Laleva, St. Kerekov, D. Pavlov, Iv. Glavchev. Obtaining of Modifiers for Reduced Friction by Еsterification of Waste Glycerol from Biodiesel Production and Sylfat 2.
Chemical Engineering and Science. 2015; 3(1):1-6. doi: 10.12691/ces-3-1-1.
Correspondence to: Iv. Glavchev, University of Chemical Technology and Metallurgy, 1756 Sofia, Bulgaria. Email:
ivgl@uctm.eduAbstract
The esterification of waste glycerol from biodiesel production (WG) ore pure glycerol (PG) with Sylfat 2 were made by catalyst 3% titanium alcoholate (TiAl) for 3 h at 150°C. The quantity of glycerol in WG and the oleic acid (OA) in Sylfat 2 were made with UV-VIS spectra. There UV-VIS and FTIR spectra were shown. Some quantity of free acids was neutralized with methylamine ore with 25% water solution of NH3 and was given FTIR spectra of obtained products. All investigations for characteristics of these products were made with standard method by four ball machine. From WG ore PG and Sylfat 2 were obtained the valuable friction modifiers, comparable with standard compounds.
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