@article{wjce2019724,
author={Habekost, Achim},
title={Simulation and Fitting of Cyclic Voltammetry and Chronoamperometry Curves of Electrochemical Reactions with Different Mechanisms ¡ª A Didactic Perspective},
journal={World Journal of Chemical Education},
volume={7},
number={2},
pages={53--64},
year={2019},
url={http://pubs.sciepub.com/wjce/7/2/4},
issn={2375-1657},
abstract={Electrochemical simulations are presented to introduce students to the capabilities of cyclic voltammetry (CV). The systems chosen involve one and two-electron transfers, and can be delineated with CV as being reversible, quasi-reversible, or irreversible. The rate constants for the electron transfer can be estimated by the theory of Nicholson and Shain. DigiElch, professional<SUP>?</SUP> provides the opportunity of fitting experimental CVs after assuming a reaction scheme. We will demonstrate data fitting for two different mechanisms, electron transfer E and electron transfer followed by a chemical reaction with a subsequent electron transfer of the product ECE.},
doi={10.12691/wjce-7-2-4}
publisher={Science and Education Publishing}
}