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<ArticleSet>
<Article>
<Journal>
<PublisherName>Science and Education Publishing</PublisherName>
<JournalTitle>World Journal of Chemical Education</JournalTitle>
<Issn>2375-1657</Issn>
<Volume>5</Volume>
<Issue>2</Issue>
<PubDate PubStatus="epublish">
<Year>2017</Year>
<Month>3</Month>
<Day>22</Day>
</PubDate>
</Journal>
<ArticleTitle>Application of Differential Scanning Calorimetry in an Organic Chemistry Laboratory Course: Development of a Binary Phase Diagram of Cis/Trans-1, 2-Dibenzoylethylene</ArticleTitle>
<FirstPage>46</FirstPage>
<LastPage>52</LastPage>
<Language>EN</Language>
<AuthorList>
<Author>
<FirstName>Ronald P.</FirstName>
<LastName>D'Amelia</LastName>
<Affiliation>Department of Chemistry, Hofstra University, Hempstead, NY 11549, United States</Affiliation>
</Author>
<Author>
<FirstName>Brett</FirstName>
<LastName>Johnson</LastName>
</Author>
<Author>
<FirstName>Shivnath</FirstName>
<LastName>Mazumder</LastName>
</Author>

</AuthorList>
<ArticleIdList>
<ArticleId IdType="pii">WJCE2017524</ArticleId>
<ArticleId IdType="doi">10.12691/wjce-5-2-4</ArticleId>
</ArticleIdList>
<History>
<PubDate PubStatus="received">
<Year>2016</Year>
<Month>10</Month>
<Day>10</Day>
</PubDate>
<PubDate PubStatus="revised">
<Year>2017</Year>
<Month>2</Month>
<Day>23</Day>
</PubDate>
<PubDate PubStatus="accepted">
<Year>2017</Year>
<Month>3</Month>
<Day>20</Day>
</PubDate>
</History>
<Abstract>In organic chemistry lab it is important to give students hands-on experiences to help them further their understanding of important chemistry topics. Binary phase diagrams incorporate many of these topics into a single graph. Differential Scanning Calorimetry (DSC) has been shown to produce data to make binary phase diagrams for alloys; however, it is more difficult to produce these diagrams using non-metal organic compounds. The purpose of this experiment was to determine if the DSC could be used to give students a challenging, yet doable experiment to prepare a binary phase diagram and determine the eutectic composition for the mixture of cis/trans-1,2-dibenzoylethylene. The conclusions from this work are: (i) The eutectic composition for cis/trans-1,2-dibenzoylethylene is at the weight percent of 30% cis and 70% trans which corresponds to an onset melting temperature of 93.5&#176;C; (ii) as the cis increased from a weight percent of 30% the melt temperature also increased; (iii) as the trans increased from a weight percent of 70% the melt temperature also increased; (iii) the DSC produced sufficient data necessary to develop a binary phase diagram of peak melt temperatures vs the weight percent of the cis isomer; (iv) the DSC could be incorporated into an organic chemistry lab to enhance student's knowledge of important topics while giving them an experience working with advanced laboratory thermal instruments.</Abstract>
</Article>
</ArticleSet>
