<?xml version="1.0" encoding="UTF-8"?>
<records>
<record>
<language>eng</language>
<publisher>Science and Education Publishing</publisher>
<journalTitle>World Journal of Chemical Education</journalTitle>
<eissn>2375-1657</eissn>
<publicationDate>2017-03-22</publicationDate>
<volume>5</volume>
<issue>2</issue>
<startPage>46</startPage>
<endPage>52</endPage>
<doi>10.12691/wjce-5-2-4</doi>
<publisherRecordId>WJCE2017524</publisherRecordId>
<documentType>article</documentType>
<title language="eng">Application of Differential Scanning Calorimetry in an Organic Chemistry Laboratory Course: Development of a Binary Phase Diagram of Cis/Trans-1, 2-Dibenzoylethylene</title>
<authors>
<author>
<name>Ronald P. D'Amelia</name>
<email>Ronald.p.damelia@hofstra.edu</email>
<affiliationId>1</affiliationId>
</author>
<author>
<name>Brett Johnson</name>
<affiliationId>1</affiliationId>
</author>
<author>
<name>Shivnath Mazumder</name>
<affiliationId>1</affiliationId>
</author>

</authors>
<affiliationsList>
<affiliationName affiliationId="1">Department of Chemistry, Hofstra University, Hempstead, NY 11549, United States</affiliationName>


</affiliationsList>
<abstract language="eng">In organic chemistry lab it is important to give students hands-on experiences to help them further their understanding of important chemistry topics. Binary phase diagrams incorporate many of these topics into a single graph. Differential Scanning Calorimetry (DSC) has been shown to produce data to make binary phase diagrams for alloys; however, it is more difficult to produce these diagrams using non-metal organic compounds. The purpose of this experiment was to determine if the DSC could be used to give students a challenging, yet doable experiment to prepare a binary phase diagram and determine the eutectic composition for the mixture of cis/trans-1,2-dibenzoylethylene. The conclusions from this work are: (i) The eutectic composition for cis/trans-1,2-dibenzoylethylene is at the weight percent of 30% cis and 70% trans which corresponds to an onset melting temperature of 93.5&#176;C; (ii) as the cis increased from a weight percent of 30% the melt temperature also increased; (iii) as the trans increased from a weight percent of 70% the melt temperature also increased; (iii) the DSC produced sufficient data necessary to develop a binary phase diagram of peak melt temperatures vs the weight percent of the cis isomer; (iv) the DSC could be incorporated into an organic chemistry lab to enhance student's knowledge of important topics while giving them an experience working with advanced laboratory thermal instruments.</abstract>
<fullTextUrl format="pdf">http://pubs.sciepub.com/wjce/5/2/4/wjce-5-2-4.pdf</fullTextUrl>
<keywords language="eng"><keyword>upper-division undergraduate</keyword>
<keyword>laboratory instruction</keyword>
<keyword>organic chemistry</keyword>
<keyword>hands-on learning</keyword>
<keyword>instrumental methods</keyword>
<keyword>phases diagrams</keyword>
<keyword>eutectic</keyword>
<keyword>cis/trans 1</keyword>
<keyword>2 dibenzoylethylene</keyword>
<keyword>Differential Scanning Calorimetry</keyword>
</keywords>
</record>
</records>
