Science and Education Publishing World Journal of Chemical Education 2375-1657 4 5 2016 10 27 An Undergraduate-Level Electrochemical Investigation of Gold Nanoparticles-Modified Physically Small Carbon Electrodes 93 100 EN Shaneel Chandra School of Medical and Applied Sciences, Building 6, Central Queensland University, Bruce Highway, North Rockhampton QLD 4702, Australia Wycliff Tupiti Sevlin Singh Zafiar Naaz Pritika K. Kishor Archana Goundar Malina Fakraufon Surendra Prasad WJCE2016451 10.12691/wjce-4-5-1 2016 7 25 2016 8 18 2016 10 25 This paper reports an undergraduate experiment based on analytical chemistry, electrochemistry and materials science of carbon microelectrodes. The modification of the electroactive surface of the carbon microelectrode was done using gold nanoparticles electrodeposited from gold solution. To determine the changes on the surface, the electrode was subjected to simple optical microscopy. Next, the electrode was characterized using fast-scan cyclic voltammetry of two known electrochemical redox markers: hexaamineruthenium(III) chloride and potassium hexacyanoferrate (III), i.e. potassium ferricyanide. The redox behavior of both markers demonstrated the change in electrode surface. After modification, the ferricyanide reduction peaks were observed to increase significantly, as a consequence of accelerated electron transfer. Furthermore, changes in wave slope and half-wave potentials (E½) of the redox waves also confirmed an altered electrode surface that students can logically trace back to the modification. The electrode tip dimension was also determined using a modified form of the Cottrell equation, confirming the tip size to be 2.0 µm. The discussion of these results enables an understanding of electrochemistry, analytical chemistry and materials chemistry, and presents an excellent opportunity to apply these in an undergraduate setting.