eng Science and Education Publishing World Journal of Chemical Education 2375-1657 2023-01-16 11 1 1 3 10.12691/wjce-11-1-1 WJCE20231111 article Sanjeev Rachuru 1 Devarakonda A. Padmavathi 2 V. Jagannadham jagannadham1950@yahoo.com 2 Department of Chemistry, Geethanjali College of Engineering and Technology, Cheeryal-501301, Telangana, India Department of Chemistry, Osmania University, Hyderabad-500007, India The pKa of Cyclohexatriene (Benzene) is 43. And that of Cyclopentadiene and Cycloheptatriene are 15 and 36 respectively. In the ascending order of number of carbon atoms of the three cyclic hydrocarbons, Cyclohexatriene lies between Cyclopentadiene and Cycloheptatriene. It is a tempting belief of undergraduate chemists who begin to pursue their undergraduate course that the pKas will be in the same increasing order with increase in ring size. But surprisingly pKa of Cyclohexatriene is more than that of either Cyclopentadiene and or Cycloheptatriene. Suitable explanations are given. http://pubs.sciepub.com/wjce/11/1/1/wjce-11-1-1.pdf Cyclohexatriene Cyclopentadiene Cycloheptatriene and pK_a