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Greetings! I hope you are well.

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Welcome to the April, 2013 edition of SciEP newsletter, providing monthly summaries of articles on science & education related topics of interest to scientist and professionals. The mission of our journals is to provide an open access forum for publishing new findings on issues pertinent to scientific and academic field. We also invite you to submit original research papers, review articles, short reports, or case studies are considered for publication in our Multidisciplinary Journals.

American Journal of Public Health Research
DOI: 10.12691/ajphr-1-1-3

The Implementation of a Tele-Homecare System with Service Oriented Architecture and HL7 Message Transmission Standard
Ching-Sung Wang

American Journal of Medical and Biological Research
DOI: 10.12691/ajmbr-1-1-2

The Influence of Ethanol on Pyruvate Kinases Activity in Vivo, in Vitro, in Silico
Lelevich Sergey Vladimirovich, Khrustalev Vladislav Victorovich, Barkovsky Eugene Victorovich, Shedogubova Tatyana Aleksandrovna

American Journal of Medical Sciences and Medicine
DOI: 10.12691/ajmsm-1-1-1

Clinical and Histological Features in Wegener Granulomatosis
Li Cavoli Gioacchino, Passantino Rita, Bono Luisa, Tortorici Calogera, Ferrantelli Angelo, Giammarresi Carlo, Rotolo Ugo

American Journal of Infectious Diseases and Microbiology
DOI: 10.12691/ajidm-1-1-2

The Curse of Lymphatic Filariasis: Would the Continual Use of Diethylcarbamazine Eliminate this Scourge in Papua New Guinea?
Anne Lanham, Lillian Mwanri

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American Journal of Cardiovascular Disease Research
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Label_Title

Dear Label_Name,

Greetings! I hope you are well.

I am writing on behalf of an international publishing house, Science and Education Publishing, USA (http://www.sciepub.com).

Science and Education Publishing (SciEP) is a multidisciplinary open access publisher of Journals covering the fields of Science, Technology and Medicine. All SciEP publications are subject to high-quality peer review, editorial and production processes and are freely available online.

Welcome to the April, 2013 edition of SciEP newsletter, providing monthly summaries of articles on science & education related topics of interest to scientist and professionals. The mission of our journals is to provide an open access forum for publishing new findings on issues pertinent to scientific and academic field. We also invite you to submit original research papers, review articles, short reports, or case studies are considered for publication in our Multidisciplinary Journals.

American Journal of Public Health Research
DOI: 10.12691/ajphr-1-1-3

The Implementation of a Tele-Homecare System with Service Oriented Architecture and HL7 Message Transmission Standard
Ching-Sung Wang

American Journal of Medical and Biological Research
DOI: 10.12691/ajmbr-1-1-2

The Influence of Ethanol on Pyruvate Kinases Activity in Vivo, in Vitro, in Silico
Lelevich Sergey Vladimirovich, Khrustalev Vladislav Victorovich, Barkovsky Eugene Victorovich, Shedogubova Tatyana Aleksandrovna

American Journal of Medical Sciences and Medicine
DOI: 10.12691/ajmsm-1-1-1

Clinical and Histological Features in Wegener Granulomatosis
Li Cavoli Gioacchino, Passantino Rita, Bono Luisa, Tortorici Calogera, Ferrantelli Angelo, Giammarresi Carlo, Rotolo Ugo

American Journal of Infectious Diseases and Microbiology
DOI: 10.12691/ajidm-1-1-2

The Curse of Lymphatic Filariasis: Would the Continual Use of Diethylcarbamazine Eliminate this Scourge in Papua New Guinea?
Anne Lanham, Lillian Mwanri

We have released issues of some journals on February 2013.
American Journal of Public Health Research
American Journal of Medical Sciences and Medicine
American Journal of Medical and Biological Research
American Journal of Pharmacological Sciences
American Journal of Clinical Medicine Research
American Journal of Nursing Research
American Journal of Cancer Prevention
American Journal of Medicine Studies
American Journal of Infectious Diseases and Microbiology
American Journal of Cardiovascular Disease Research
American Journal of Biomedical Research
American Journal of Mechanical Engineering
American Journal of Microbiological Research
Journal of Preventive Medicine
American Journal of Food and Nutrition
American Journal of Hypertension Research
American Journal of Sports Science and Medicine
Journal of Cancer Research and Treatment
American Journal of Zoological Research
Journal of Biomedical Engineering and Technology
American Journal of Microbiological Research
Biomedical Science and Engineering

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Label_Title

Dear Label_Name,

Greetings! I hope you are well.

I am writing on behalf of an international publishing house, Science and Education Publishing, USA (http://www.sciepub.com).

Science and Education Publishing (SciEP) is a multidisciplinary open access publisher of Journals covering the fields of Science, Technology and Medicine. All SciEP publications are subject to high-quality peer review, editorial and production processes and are freely available online.

Welcome to the April, 2013 edition of SciEP newsletter, providing monthly summaries of articles on science & education related topics of interest to scientist and professionals. The mission of our journals is to provide an open access forum for publishing new findings on issues pertinent to scientific and academic field. We also invite you to submit original research papers, review articles, short reports, or case studies are considered for publication in our Multidisciplinary Journals.

American Journal of Public Health Research
DOI: 10.12691/ajphr-1-1-3

The Implementation of a Tele-Homecare System with Service Oriented Architecture and HL7 Message Transmission Standard
Ching-Sung Wang

American Journal of Medical and Biological Research
DOI: 10.12691/ajmbr-1-1-2

The Influence of Ethanol on Pyruvate Kinases Activity in Vivo, in Vitro, in Silico
Lelevich Sergey Vladimirovich, Khrustalev Vladislav Victorovich, Barkovsky Eugene Victorovich, Shedogubova Tatyana Aleksandrovna

American Journal of Medical Sciences and Medicine
DOI: 10.12691/ajmsm-1-1-1

Clinical and Histological Features in Wegener Granulomatosis
Li Cavoli Gioacchino, Passantino Rita, Bono Luisa, Tortorici Calogera, Ferrantelli Angelo, Giammarresi Carlo, Rotolo Ugo

American Journal of Infectious Diseases and Microbiology
DOI: 10.12691/ajidm-1-1-2

The Curse of Lymphatic Filariasis: Would the Continual Use of Diethylcarbamazine Eliminate this Scourge in Papua New Guinea?
Anne Lanham, Lillian Mwanri

We have released issues of some journals on February 2013.
American Journal of Public Health Research
American Journal of Medical Sciences and Medicine
American Journal of Medical and Biological Research
American Journal of Pharmacological Sciences
American Journal of Clinical Medicine Research
American Journal of Nursing Research
American Journal of Cancer Prevention
American Journal of Medicine Studies
American Journal of Infectious Diseases and Microbiology
American Journal of Cardiovascular Disease Research
American Journal of Biomedical Research
American Journal of Mechanical Engineering
American Journal of Microbiological Research
Journal of Preventive Medicine
American Journal of Food and Nutrition
American Journal of Hypertension Research
American Journal of Sports Science and Medicine
Journal of Cancer Research and Treatment
American Journal of Zoological Research
Journal of Biomedical Engineering and Technology
American Journal of Microbiological Research
Biomedical Science and Engineering

We are pleased to announce that submissions are now being accepted for peer review for all the journals across all our subject areas in SciEP.

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Optical, Structural and Morphological Characterization of Germanium Doped Cesium Tin Triiodide for Perovskite Solar Cells Applications

Marion Mogusu*, Duke Oeba, Cliff Mosiori

Department of Physics, Faculty of Science, Egerton University, P.O. Box 536-20115, Egerton, Kenya

Abstract: In this work, germanium doped cesium tin triiodide (CsSnI₃-Ge) perovskite thin films, incorporated with a 5mole% germanium (Ge) concentration were deposited on fluorine doped tin (IV) oxide (FTO) substrates using spin coating technique and the films were synthesized under different spin coating speeds. Ge was used as a dopant to curb the problem of the rapid oxidation of tin (II) ions (Sn²⁺) to tin (IV) ions (Sn⁴⁺) in the presence of oxygen. Optical measurements were done using ultraviolet visible (UV-Vis) spectrophotometer, structural measurements were carried out using an X-ray diffraction (XRD) machine and the morphological analysis was done using a scanning electron microscope (SEM). The CsSnI₃-Ge layer deposited at a spin coating speed of 4000 revolutions per minute(rpm) displayed the highest absorbance with a band gap value in the range of 2.85 eV to 3.36 eV which was higher than the ideal value of ~1.5 eV. Structural analysis on the different CsSnI₃-Ge films displayed a consistent orthorhombic structure across all samples and SEM images revealed almost identical crystallite sizes. Generally, the perovskite film synthesized by spin coating speed of 4000 rpm displayed higher absorbance, higher crystallinity and a possibly uniform film morphology making it the optimal layer for solar cell applications.

Keywords: Perovskites, tin oxidation, spin coating, thin films

Received June 06, 2025; Revised July 08, 2025; Accepted July 15, 2025

Citation: Marion Mogusu, Duke Oeba, Cliff Mosiori, Optical, Structural and Morphological Characterization of Germanium Doped Cesium Tin Triiodide for Perovskite Solar Cells Applications. International Journal of Physics, 13 (3). 62-68. January 2025. doi:10.12691/ijp-13-3-3

1. Introduction

Mankind has been looking for a source of energy that is commercially viable and environmentally sustainable for many years. The current global demand for power is at 16 TW and is estimated to increase beyond 30 TW by 2050 [1]. Therefore, intense research is being carried out to get power generation systems to cover this expected demand. Most of the energy consumed is produced from non-renewable resources such as coal, petroleum, uranium, and natural gas which leads to their depletion at a faster rate causing a series of environmental problems [2]. It is now confirmed that the burning of fossil fuels alone cannot cover the expected hike in energy demand. It has been proposed that renewable energy sources offer an alternative for power generation that include nuclear, tidal, hydropower, geothermal, wind and solar energies [3].

Due to their direct sunlight-to-electricity conversion, photovoltaic (PV) solar cells are a promising and preferred choice for power generation among researchers. Solar energy as opposed to wind or hydropower is not location dependent and is available almost anywhere on earth. The direct conversion of sunlight to electricity by solar panels makes them a suitable choice as opposed to wind and hydropower which depend on kinetic energy conversion to electric energy, an energy transfer process which is prone to losses. Solar energy is still evolving, and a lot of research is being conducted to improve their efficiency, stability and cost reduction. In this work, perovskites are investigated owing to their cost effectiveness and high efficiency. However, their long-term stability is still something to be looked at.

Perovskites are compounds that have ABX₃ as their general formula. A, B and X are three different species where A and B are cations and X is an anion. Perovskite materials have a broad absorption range when it comes to the solar spectrum with just a thin layer of material making them greatly efficient. The vast potential of perovskite solar cells (PSCs) is evident since their power conversion efficiency (PCE) has risen gradually from 3.8% to 25.2% in the last decade, while other technologies took nearly 30 years to witness this milestone [1]. PSCs can be synthesized in laboratories using wet chemical techniques with the help of simple low-cost techniques, such as spin coating, dip coating, screen printing, dual source evaporation techniques, etc. [1]. Despite all the merits, poor device stability, short lifetime, and toxicity of lead are creating hindrances in the path of commercialization of PSCs.

Among the several low-toxicity cations that have been proposed for replacing lead in perovskites, Sn based perovskites have shown the highest efficiency (PCE > 14%) and are gravitating towards 20% PCE [4]. Cesium-based all-inorganic PSCs have attracted increasing attention due to their advantage of superior thermal and phase stability [5]. The perovskite layer is the vital part of the PSC and is formed when a solution containing the perovskite sample is placed onto the electron transport layer (ETL) or hole transport layer (HTL) and permitted to crystallize. This perovskite layer serves as the main material for light absorption in the device, it absorbs light consequently generating electron-hole pairs. In this work, cesium tin triiodide (CsSnI₃) perovskite is doped with Ge to exert control over charge carrier lifetime, Sn oxidation and defect density recombination which results to improved stability for solar cell applications [6]. In this study the synthesis of CsSnI₃-Ge was done via a low-cost solution mixing process followed by spin coating for deposition.

2. Materials and Methods

2.1. Materials

Commercial FTO-coated glass substrates formed the foundational base for deposition and the essential chemical components in this study included cesium (II) iodide powder, tin (II) iodide powder, and Ge powder. These materials were crucial for the desired perovskite structure. Solvents such as dimethylformamide (DMF), dimethyl sulfoxide (DMSO) and chlorobenzene played integral roles in solution preparation and film processing. Distilled water, ethanol and acetone were indispensable for cleaning throughout the synthesis process. A magnetic stirrer aided in solution mixing, a vacuum oven was used for drying and a spin coater ensured uniform substrate coating of the perovskite.

2.2. Methodology

2.2.1. FTO Substrate Cleaning

Before deposition, the FTO substrates underwent a multi-stage cleaning process. First, the substrates surfaces were wiped using a clean residue free wipe dipped in acetone to remove any dust, dirt and fingerprint. This was followed by further cleaning using ethanol to remove organic contaminants like grease and oil. The substrates were then rinsed with distilled water to remove any residue that remained from the organic solvents. Finally, they were dried for 15 minutes in a vacuum oven at a low temperature of 50°C to avoid possible damage to the FTO substrate coatings.

2.2.2. Synthesis and Deposition of CsSnI₃-Ge thin films

CsSnI₃-Ge solution was obtained by combining 0.65 g ± 0.01 g CsI, 0.93 g ± 0.01 g SnI₂ powders and a 5mole% Ge concentration which is equivalent to 0.036 g ± 0.001 g of Ge powder and dissolved them in 15 ml DMF and DMSO mixed solution mixed at 1:2 ratio. The solution was stirred well for complete dissolution using a magnetic stirrer at 80°C.100 µL of the resultant CsSnI₃-Ge solution was then spin coated onto each of the three FTO substrates with a single spin cycle rotation with speeds of 2000 rpm, 3000 rpm and 4000 rpm respectively for 60 seconds each. 100 µL of antisolvent chlorobenzene was applied 20 seconds before the end of each spin cycle followed by drying of the films in a vacuum oven at room temperature for 30 minutes. Annealing of the films was done at 120°C for 30 minutes.

2.2.3. Characterization of the CsSnI₃-Ge thin films

The optical properties of the deposited films were measured using the UV-Vis spectrophotometer located at the department of Physics at Egerton University to analyze optical absorbance. The XRD patterns of the three perovskite films were obtained using a Rigaku Ultima IV X-ray diffractometer at the University of Michigan with Cu-Kα radiation (40 kV/ 44 mA) of wavelength λ = 1.5406 Å at an angle 2θ. The SEM images were captured using a FEI Nova 200 Nano lab system located at the University of Michigan under a 20,000 X magnification.

3. Results and Discussion

3.1. Optical Properties of CsSnI₃-Ge thin films

A material’s photoconductivity depends on how much light energy is absorbed by the material [7]. Therefore, absorptivity is crucial in the electricity production process. In this investigation, CsSnI₃-Ge layer was deposited via spin coating at three distinct speeds of 2000 rpm, 3000 rpm and 4000 rpm on FTO glass substrates at a fixed time of 60 seconds.

3.1.1. Absorbance of CsSnI₃-Ge thin films

The graphical representations of the optical absorbance of the CsSnI₃-Ge layer measured as a function of wavelength show a strong absorption peak in the visible light spectrum for all the three samples and then drops above 500 nm wavelength. This is in close agreement with the absorption range of perovskites which is between 400-750 nm and decreases above 600 nm [8]. Absorption is noted to be higher at shorter wavelengths as compared to longer wavelengths in all the layers. The strong absorption peaks can be attributed to direct band transitions of electrons from the valence band to the conduction band in relation to the band gap energy of the material [9]. This agrees with the theoretical relationship between wavelength (λ) and bang gap energies [10]:

[picture] | (1)

Where is the Planck’s constant, c the speed of light and the band gap of the material. As a result, the strong absorption peaks observed at the specific wavelengths could correspond to the band gap energy of the material. One of the products from the possible Sn oxidation in the perovskite layer is SnI₄ and [11] identified its unique absorption spectra. The strong SnI₄ peaks tend to appear at about 380 nm wavelength which can further explain the strong peaks appearing at about the same wavelength in this study. These peaks are consistent in all the figures and could suggest the presence of SnI₄ in all three films.

The absorbance spectrums displayed in the figures generally show that CsSnI₃-Ge perovskite is a good absorber of photons. Figure 1 (a) represents the absorbance spectrum of the CsSnI₃-Ge perovskite layer deposited at a spin coating speed of 2000 rpm. Absorbance is high at lower wavelengths between 350-450 nm then drops (<0.2 a. u) at 450 nm and remains constant above 500 nm wavelength. The suspected yellow phase perovskite determined from the band gap value is said to only absorb light at shorter wavelengths [12] which can explain the blue shift in the peaks of these perovskite films. The sharp peaks observed at the lower wavelengths for all the three films could suggest the presence of other phases corresponding to the additional peaks also found from the XRD findings.

The thin film deposited at 3000 rpm spin coating speed displays an almost similar absorbance spectrum as the 2000 rpm thin film as is seen in figure 1 (b). Absorbance is high at lower wavelengths of below 450 nm drops above 460 nm and remains nearly constant above 500 nm. Both layers (2000 rpm, 3000 rpm thin films) display a high absorbance of approximately 0.66 a.u in the lower region of visible light range. Spin coating speed affects the thickness of the thin films [13] however, the difference in thickness between the two films is negligible. This accounts for their nearly identical absorption spectra at spin coating rotational speeds of 2000 and 3000 rpm.

Figure 1. (a): Absorbance spectra of CsSnI₃-Ge thin film deposited at a speed rotation of 2000 rpm. (b): Absorbance spectra of CsSnI₃-Ge thin film deposited at a speed rotation of 3000 rpm. (c): Absorbance spectra of CsSnI3-Ge thin film deposited at a speed rotation of 4000 rpm

Figure 1 (c) displays the absorbance spectrum of the CsSnI₃-Ge thin films deposited at a spin coating speed of 4000 rpm. This speed displays a relatively high absorbance of approximately 0.77 a. u in the visible light region. Absorbance is relatively high in the 350-450 nm range with the display of high intensity peaks. It then drops above 450nm and then remains nearly constant above 500 nm (<0.3 a. u). It has been shown that the absorbance of tin-based perovskites is easily influenced by the film thickness and the crystal quality of the perovskite [14]. These reasons could have resulted in peak intensities variations at different speeds.

The absorbance spectrum of the thin film resultant from 3000 rpm speed had a slightly lower absorbance though with a similar trend as the 2000 rpm counterpart thin film. This was why they exhibited almost identical thickness. It was suggested that the spin coating speed of 2000 rpm and 3000 rpm have negligible influence on variation of thickness in CsSnI₃-Ge thin film. Comparing all three samples, it can be suggested that the layers produced at speeds of 2000 rpm and 3000 rpm display the lowest absorbance across the visible light spectrum because they formed thicker films due to lower speeds. The layers have a chance of suffering from scattering losses causing the low absorption [13]. It was also suggested that scattering losses may also be caused by the roughness and non-uniform surfaces of the resultant 2000 rpm and 3000 rpm speed layers as seen in the SEM images in figure 5 (a) and 5 (b).

Finally, the thin film deposited at 4000 rpm speed displayed the highest absorbance as compared to the other two samples seen in figure 2. Smoother films attract higher absorbance because there is enhanced light trapping as there is minimal light scattering at the surface of the film [15]. This could explain the higher absorbance of the layer deposited at 4000 rpm speed compared to its counterparts as a result. Therefore, higher speeds possibly result in thinner, smoother films. Additionally, thinner films have less material, which means there are fewer opportunities for light to be scattered or reflected within the film. As a result, more light is absorbed by the material. Perovskites are expected to be good absorbers of light hence the sample with the highest absorption is preferred. In this study, the CsSnI₃-Ge thin film resulting from the 4000 rpm spin speed is the optimal film.

Figure 2. Absorbance spectra of CsSnI₃-Ge thin film deposited at different speed rotation: 2000 rpm, 3000 rpm and 4000 rpm

3.1.2. Bandgap of the CsSnI₃-Ge thin films

The band gap of the three perovskite films deposited at different spin coating speeds of 2000 rpm, 3000 rpm and 4000 rpm were determined via the Tauc plot using the Tauc relation:

[picture] | (2)

Where is the photon energy, α the absorption coefficient, the material’s dependent constant and the optical bandgap of the material. The absorption coefficient was obtained using equation (3):

[picture] | (3)

A graph of was plotted as a function of as shown in figure 3. The bandgap was determined by extrapolating the linear region(s) of the curve. The point where the lines intercepted the x-axis is the band gap.

Figure 3. Tauc plots for direct bandgap calculation of CsSnI₃-Ge thin films deposited at different speed rotations: 2000 rpm, 3000 rpm and 4000 rpm

Analysis suggested that all the films display almost similar band gap values that lie between 2.85 eV to 3.36 eV. This observation suggested that spin coating speeds had no serious influence or impact on the band gap of the CsSnI₃-Ge thin films. However, these values are higher than the reported literature values at ~ 1.5 eV [16]. This higher band gap could be attributed to the partial doping with Ge which may have not fully dissolved in the DMF/DMSO solution and may have caused the native oxidation of Sn²⁺ vacancies to Sn⁴⁺ leading to the generation of Ge rich regions forming p-type orientations. The ideal band gap for most single-junction solar cells has a range of 1.5 eV to 2.4 eV based on the Shockley–Queisser limit. It is important to note that band gap can be easily tuned by adjusting parameters like doping and temperature during deposition. Tenability is possible since tin trihalide perovskites are also known to have large band gaps which in turn lead to a low absorption capacity [12].

Yellow phase compounds are characterized by large band gaps which could be the reason behind the huge band gap range (2.85 eV to 3.36 eV) for the perovskite in this study. This is in close agreement with the reported band gap value of 2.99 eV of yellow orthorhombic CsSnI₃ perovskite phase, indicating that the structure could have undergone phase transition at some point [12]. CsSnI₃ can also completely convert into a non-perovskite phase, Cs₂SnI₆ under storage in air for short periods of 48 hours or less which is also yellow in color [17,29] making this another possible reason for the wider band gap in this study. However, the band gap of Cs₂SnI₆ is 1.48 eV which is narrower than the value in this study further suggesting the formation of the yellow orthorhombic CsSnI₃ perovskite phase and elimination of the possibility of the Cs₂SnI₆ phase formation.

3.2. Structural Analysis of CsSnI₃-Ge thin films

Figure 4 is an XRD pattern of the three samples deposited at different spin coating speeds of 2000 rpm, 3000 rpm and 4000 rpm. The successful synthesis of the perovskite structures was confirmed by the sharp peaks which correspond to specific planes in the crystal structures. Higher peaks are as a result of a greater degree of crystallinity and the sharpness of the peaks can also indicate the crystallinity degree. Nearly all the peaks from the samples at different spin speeds of 2000 rpm, 3000 rpm and 4000 rpm have similar diffraction planes indicating that they might all have a similar crystalline phase. This shows that the change in spin coating speeds did not alter the crystal structure of the perovskite. However, there are two missing peaks in the 4000 rpm sample that are present in the 2000 rpm and 3000 rpm samples. These peaks are positioned at approximately 27.6° and 48.7° 2θ angles. This can be attributed to the higher kinetic energy experienced at higher speeds which may have altered the preferred orientation of the crystals within the film [23]. This induced the alignment of crystals in a specific direction which may have resulted in the suppression of the peaks in the 4000 rpm sample pattern.

CsSnI₃ is a unique phase change perovskite and can exist in four polymorphic phases including the black tetragonal (Bβ), black cubic (Bα), black orthorhombic (Bγ) and yellow orthorhombic (Yγ). On air exposure, the Bγ phase can change to the Yγ phase due to the oxidation of Sn [18]. Peaks of about 27° and 29°are known to correspond to Bγ CsSnI₃ phase of the (202) plane [19] therefore, in this study the 26.5° and 27.6° peak angles could suggest the presence of CsSnI3 perovskite. However, only three of the characteristic peak angles reported for the Bγ CsSnI3 [20] match the peak angles in this study which could suggest the presence of a different phase. It can be concluded that the observed XRD patterns for all the three thin films synthesized at different spin coating speeds seen in figure 4 are in good agreement with the reported orthorhombic structure of yellow CsSnI3 with space group pnma [21]. They also found that the Yγ CsSnI3 polymorph is the most stable at room temperature when exposed to organic solvents as compared to the Bγ CsSnI₃ polymorph. This also corresponds to the suspected structure determined during band gap calculation in section 3.1.2. These results further confirm the presence of the Yγ CsSnI₃ crystal structure.

The reported characteristic peaks of CsI and SnI₂ are about 12.8° and 27.6° respectively [22]. In this study, no intensity peak is observed at 12.8° but there is a high intensity peak at about 27.6°. This could mean that there was an excess of SnI₂ residue due to the incomplete solubility of Ge where a complete reaction with SnI₂ was expected. On the other hand, the existence of no peak at around 12.8° could mean that there were no residues left of CsI. The additional short peaks could suggest the presence of other phases [23]. Nearly all the peaks from the samples at different spin coating speeds of 2000 rpm, 3000 rpm and 4000 rpm have similar intensities with the 4000 rpm thin film displaying slightly higher intensity peaks. Higher intensity peaks correspond to better/higher crystallinity which is preferred because device stability is highly dependent on the crystallinity of the perovskite layer [24]. It can be concluded that higher speeds promote crystal growth as seen from the increased intensity of the peaks with an increase in spin coating speeds.

Figure 4. XRD patterns of the CsSnI₃-Ge thin films deposited on FTO glass substrate at different speed rotation: 2000 rpm, 3000 rpm and 4000 rpm

3.3. Morphological Analysis of CsSnI₃-Ge Layers

The morphological analysis of the surface of the three films synthesized at different spin coating speeds of 2000 rpm, 3000 rpm and 4000 rpm were determined using SEM yielding the images displayed in figures 5 (a), 5 (b) and 5(c). During measurement, the operating conditions for the imaging remained consistent for all the three samples. The accelerating voltage 5.00 kV and a beam current of 0.40 nA with a working distance (WD) of 5.0 -5.1 mm were maintained for all the samples. The film crystals and sizes are equally and evenly distributed. All the three top view SEM images displayed rhombic shaped crystallites. However, the SEM images for the three samples were found to have slightly different morphologies which is evidence that spin coating speed affects the morphology of thin films.

From the images shown in figure 5 (a), (b) and (c) there is no significant difference in crystal size. Due to the incomplete solubility of Ge, the resultant CsSnI₃ perovskite phase possibly undergoes oxidation from Sn²⁺ to Sn⁴⁺ during crystallization. This oxidation could lead to incomplete surface coverage [25]. It can also be seen that spin coating speed has an impact on the uniformity of the CsSnI₃-Ge perovskite layer. Morphology control in Sn based perovskites can be challenging because of their rapid oxidation. The 2000 rpm layer appears to have incomplete surface coverage with layer grains as seen in figure 5 (a). The surface also appears to be relatively rough and is likely thicker making it more prone to agglomeration. The 3000 rpm layer appears smoother and more compact in comparison to the 2000 rpm layer. The crystals seem more refined and there are fewer visible gaps. The increased centrifugal force may have resulted in the film’s improved uniformity because of the rapid spread. This also results in the formation of a thinner film which agrees with literature findings [13] that higher speeds result to thinner films [28]. However, some regions in this layer show particle agglomeration where large clusters were visible with irregularities in distribution as seen in figure 5 (b).

In the third and last image which represents the highest spin coating speed of 4000 rpm, the surface appears more uniform as compared to the other two samples mentioned above, an indication that high speeds result in more uniform films. This is because of the faster nucleation and crystallization associated with high speeds [26]. Therefore, the surface could appear smooth with less visible grain boundaries as can be seen in figure 5 (c). The smoother surface and thinner film may result from rapid solvent removal and improved solution spreading during synthesis. In solar cells, smother surfaces lead to improved charge transport and reduced charge recombination consequently minimizing leakage current [27]. Therefore, it is critical to achieve a smooth perovskite surface. Among the three samples highlighted in this study, the 4000 rpm layer possibly resulted in a smoother layer.

Figure 5. (a): CsSnI₃-Ge at 2000 rpm speed. (b): CsSnI₃-Ge at 3000 rpm speed. (c): CsSnI₃-Ge at 4000 rpm speed

4. Conclusion

This research successfully investigated the optical, structural and morphological analysis of the CsSnI₃-Ge perovskite thin films spin coated at different speeds. The CsSnI₃-Ge thin films absorption spectra reveal that spin coating speed has an effect on absorbance with the 4000 rpm thickness layer displaying the highest absorbance among the three investigated speeds. The band gap of the films was revealed to be in the range of 2.85 eV to 3.36 eV which is higher than the reported value of ~1.5 eV and this is attributed to the incomplete Ge incorporation into the CsSnI₃ perovskite which can exist in different phases. From this study, the band gap value corresponded to the Yγ CsSnI₃ perovskite phase. The XRD analysis revealed the presence of an orthorhombic phase which corresponds to the Yγ structure obtained from the optical measurements of the thin films. There is a possible presence of additional phases seen from the additional XRD peaks. The additional peaks may have resulted from defects or a thin layer of metal oxide on the surface of the film. The 4000 rpm layer displays the highest intensity peaks corresponding to better crystallinity, suggesting that higher speeds promote crystal growth.

The morphological analysis of the CsSnI₃-Ge films shows incomplete surface coverage resulting from the oxidation of Sn²⁺ to Sn⁴⁺ during crystallization due to the partial solubility of Ge powder. No significant difference in crystallite sizes is observed from the images for the different spin coating speeds. However, the surface of the 4000 rpm is likely smoother, thinner and more uniform as compared to the other two surfaces suggesting that higher speeds result in smoother, more uniform thin films. In this study, the CsSnI₃-Ge film deposited at 4000 rpm was selected as a potential candidate for fabricating a perovskite- based solar cell. Due to equipment limitations we were unable to conduct atomic force microscopy (AFM) measurements to determine the surface roughness of the films but it is recommended in future studies. An inert atmosphere or an all-vacuum environment is also recommended for the synthesis of Sn based perovskites in future research. This is to prevent the rapid native oxidation of Sn²⁺, in turn minimizing the phase inconsistencies for enhanced solar cell performance. Alternative synthesis routes for Ge doping should also be explored to attain an ideal band gap value for maximum absorption.

ACKNOWLEDGEMENTS

This work was carried out with a grant in the UNESCO-TWAS program, ‘‘Seed Grant for African Principal Investigators,’’ financed by the German Federal Ministry of Education and Research (BMBF) grant agreement No. 4500474973. The views expressed herein do not necessarily represent those of UNESCO-TWAS or BMBF.

Statement of Competing Interests

The authors declare that they have no competing interests.

List of Abbreviations

a.uAbsorbance units

DMFDimethylformamide

DMSODimethyl sulfoxide

FTOFlourine doped tin (IV) oxide

PCEPower conversion efficiency

PSCPerovskite solar cell

PVPhotovoltaic

RpmRevolutions per minute

SEMScanning electron microscope

UV-VISUltraviolet visible spectroscopy

WDWorking distance

XRDX-ray diffraction

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