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ISSN (Online): 2373-3462

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Currrent Issue: Volume 4, Number 1, 2017

Article

Electrical and Gas Sensing Behaviour of Polypyrrole/silver Sulphide Nanocomposites

1University Institute of Chemical Technology, North Maharashtra University, Jalgaon, MS


American Journal of Sensor Technology. 2017, 4(1), 10-20
doi: 10.12691/ajst-4-1-2
Copyright © 2017 Science and Education Publishing

Cite this paper:
Bharati Yeole, Tanushree Sen, Dharmesh Hansora, Satyendra Mishra. Electrical and Gas Sensing Behaviour of Polypyrrole/silver Sulphide Nanocomposites. American Journal of Sensor Technology. 2017; 4(1):10-20. doi: 10.12691/ajst-4-1-2.

Correspondence to: Satyendra  Mishra, University Institute of Chemical Technology, North Maharashtra University, Jalgaon, MS. Email: profsm@rediffmail.com

Abstract

We investigated the room temperature NH3 sensing performance of polypyrrole/silver sulphide (PPy/Ag2S) nanocomposites (NCs). Sonochemically synthesized Ag2S nanoparticles (80-100 nm) were incorporated into the PPy matrix via ultrasound-assisted in-situ polymerization. The resulting PPy/Ag2S NCs were evaluated based on structural, morphological, and electrical properties. Microscopy results revealed a uniform dispersion of Ag2S nanoparticles in the PPy matrix. We studied the effect of Ag2S nanoparticle concentration on the electrical properties and gas sensing performance of the PPy/Ag2S NCs. The current-voltage (I-V) characteristics revealed the semiconducting nature of the PPy/Ag2S NCs. An improvement in the electrical conductivity was observed for the PPy/Ag2S NC with 3 wt% Ag2S nanoparticle content. PPy/Ag2S NCs were further tested for detection of NH3 in ambient conditions. The PPy/Ag2S NCs exhibited excellent sensor response towards 100 ppm NH3 concentration at room temperature.

Keywords

References

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Article

N,N’-Diphenyldecanediamide: A Fluoride Ion Sensitive and Selective Amide

1Amity School of Applied Sciences, Amity University Haryana, Panchgaon, Manesar, Gurgaon, Haryana, India


American Journal of Sensor Technology. 2017, 4(1), 1-9
doi: 10.12691/ajst-4-1-1
Copyright © 2017 Science and Education Publishing

Cite this paper:
Meenakshi Thakran, Anek pal Gupta, Neeru Dabas. N,N’-Diphenyldecanediamide: A Fluoride Ion Sensitive and Selective Amide. American Journal of Sensor Technology. 2017; 4(1):1-9. doi: 10.12691/ajst-4-1-1.

Correspondence to: Neeru  Dabas, Amity School of Applied Sciences, Amity University Haryana, Panchgaon, Manesar, Gurgaon, Haryana, India. Email: ndabas@ggn.amity.edu

Abstract

A fluoride ion (F-) sensitive organic ligand N, N’-Diphenyldecanediamide (L1), has been synthesized by the reaction of sebacoyl chloride with aniline in presence of triethylamine at room temperature. Spectroscopic investigation revealed F- interacts strongly with L1 in comparison to other competitive anions (Cl-, Br- and NO3-) and as a consequence induces deprotonation in the NH fragment of L1. Different spectroscopic techniques such as 1H NMR, UV-Vis and fluorescence emission spectroscopy supports the fast and distinct response behavior of N, N’-substituted polymethylene diamide towards F-.

Keywords

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