American Journal of Energy Research

ISSN (Print): 2328-7349

ISSN (Online): 2328-7330

Website: http://www.sciepub.com/journal/AJER

Current Issue» Volume 3, Number 1 (2015)

Article

A Novel Integrated Hydrothermal Liquefaction and Solar Catalytic Reforming Method for Enhanced Hydrogen Generation from Biomass

1Department of Chemical and Biological Engineering, South Dakota School of Mines & Technology, Rapid City, South Dakota, USA


American Journal of Energy Research. 2015, 3(1), 1-7
DOI: 10.12691/ajer-3-1-1
Copyright © 2015 Science and Education Publishing

Cite this paper:
Anuradha Shende, Richa Tungal, Rajneesh Jaswal, Rajesh Shende. A Novel Integrated Hydrothermal Liquefaction and Solar Catalytic Reforming Method for Enhanced Hydrogen Generation from Biomass. American Journal of Energy Research. 2015; 3(1):1-7. doi: 10.12691/ajer-3-1-1.

Correspondence to: Rajesh  Shende, Department of Chemical and Biological Engineering, South Dakota School of Mines & Technology, Rapid City, South Dakota, USA. Email: rajesh.shende@sdsmt.edu

Abstract

Short energy intensive hydrothermal liquefaction (HTL) of biomass in the presence of Ni salt catalyst selectively generates H2 in the product gas and biocrude mainly containing C1-C3 acids (formic, lactic, propionic, acetic), HMF and furfural. The H2 mass balance indicated that only 3.12 vol% H2 in biomass (cotton) was released as product gas; 48.7 vol% was captured in the C1-C3 acids while the remainder H2 was trapped in oxygenated compounds and char. Continuing HTL after 120 minutes caused no further increase in gas phase H2 yields. To enhance the H2 yields with minimal energy input, solar photocatalytic reforming (PR) of the biocrude with Pt/TiO2 catalyst was investigated. Photocatalysis of activated carbon (AC) treated biocrude generated an additional H2, 17.82 wt%. H2 yields from photoreforming of simulated biocrude acid mixture and actual biocrude were compared. Enhanced H2 generation was observed with integrated HTL-PR of biomass.

Keywords

References

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[1]  Lewis, N., “Powering the Planet”, MRS Bulletin, 32 (10). 808- 820. 2007.
 
[2]  Rittmann, S., and Herwig, C., “A comprehensive and quantitative review of dark fermentative biohydrogen production”, Microbial Cell Factories, 11 (1.). 115-133. 2012.
 
[3]  Wang, D., Czernik, S., Montane, D., Mann, M., and Chornet, E., “Biomass to hydrogen via fast pyrolysis and catalytic steam reforming of the pyrolysis oils or its fractions”, Industiral & Engineering Chemistry Research, 36 (5). 1507-1518. 1997.
 
[4]  Elliot, D.C., Neuenschwander, G.G., Hart, T.R., Butner, R.S., Zacher, A.H., Engelhard, M.H., Young, J.S., and McCready, D.E., “Chemical processing in high-pressure aqueous environments. 7. Process development for catalytic gasification of wet biomass feedstocks”, Industiral & Engineering Chemistry Research, 43 (9). 1999-2004. 2004.
 
[5]  Tungal, R., and Shende, R.V., “Subcritical aqueous phase reforming of wastepaper for biocrude and H2 generation”, Energy & Fuels, 27 (6). 3194-3203. 2013.
 
Show More References
6]  Tungal, R., and Shende, R.V., “Hydrothermal liquefaction of pinewood (Pinus ponderosa) for H2, biocrude and bio-oil generation”, Applied Energy, 134. 401-412. 2014.
 
7]  Kondarides, D.L., Daskalaki, V.M., Patsoura, A., and Verykios X.E., “Hydrogen production by photo-induced reforming of biomass components and derivatives at ambient conditions”, Catalysis Letters, 122. 26-32. 2008.
 
8]  Fu, X., Long, J., Wang, Z., Leung, D.Y.C., Ding, Z., Wu, L., Zhang, Z., Li, Z., and Fu, X., “Photocatalytic reforming of biomass: A systematic study of hydrogen evolution from glucose solution”, International Journal of Hydrogen Energy, 33 (22), 6484-6491. 2008.
 
9]  Tungal, R., Shende, R.V., and Christopher, L., “Nickel catalyzed high pressure hydrothermal processing of biomass for H2 production”, Journal of Energy Power Engineering, 5. 504-514. 2011.
 
10]  Li Y, Lu G, Li S. Photocatalytic production of hydrogen in single component and mixture systems of electron donors and monitoring adsorption of donors by in situ infrared spectroscopy. Chemosphere. 2003 Aug; 52(5):843-50.
 
11]  Lanese, V., Spasiano, D., Marotta, R., Sommar, I.D., Lisi, L., Cimio, S., Andreozzi, R., 2013. Hydrogen production by photoreforming of formic acid in aqueous copper/TiO2 suspensions under UV-simulated solar radiation at room temperature, Int. J. Hydrogen Energy, 23, 9644-9654.
 
12]  Heciak,A, Morawski, A Grzmil, B, Mozia, S August–September 2013; Cu modified TiO2 photocatalysts for decomposition of acetic acid with simultaneous formation of C1–C3 hydrocarbons and hydrogen Applied Catalysis B: Environmental; Volumes 140–141,108-114.
 
13]  Maraschi, Daniele Dondi, Andrea Serra, Antonella Profumo, Armando Buttafava, Angelo Albini Swine sewage as sacrificial biomass for photocatalytic hydrogen gas production: Explorative study Andrea Speltini, Michela Sturini, Federica International journal of hydrogen energy 39 (2014) 11433 e11440.
 
14]  Ela Ero glua, ˙Inci Ero glua, Ufuk Gündüzb, Lemi Türkerc, Meral Yücelb Biological hydrogen production from olive mill wastewater with two-stage processes International Journal of Hydrogen Energy 31 (2006) 1527-153.
 
15]  Mohan, S.V., and Karthikeyan, J., “Removal of lignin and tannin colour from aqueous solution by adsorption onto activated charcoal”, Environment Pollution, 97 (1-2). 183-187. 1997.
 
16]  Mudoga, H.L., Yucel, H., and Kincal, N.S., “Decolorization of sugar syrups using commercial and sugar beet pulp based activated carbons”, Bioresource Technology, 99 (9). 3528-3533. 2008.
 
17]  Orozco, R.L., Redwood, M.D., Leeke, G.A., Bahari, A., Santos, R.C.D., and Macaskie, L.E., “Hydrothermal hydrolysis of starch with CO2 and detoxification of the hydrolysates with activated carbon for bio-hydrogen fermentation”, International Journal of Hydrogen Energy, 37 (8). 6545-6555. 2012.
 
18]  Hashimoto, K., Irie, H., and Fujishima, A., “TiO2 photocatalysis: a historical overview and future prospects”, Japanese Journal of Applied Physics, 44 (12). 8269-8285. 2005.
 
19]  Hussein, A.M., and Shende, R.V., “Enhanced hydrogen generation using ZrO2-modified coupled ZnO/TiO2 nanocomposites in the absence of noble metal co-catalyst”, International Journal of Hydrogen Energy, 39 (11). 5557-5568. 2014.
 
20]  Ni, M., Leung, M.K.H., Leung, D.Y.C., and Sumathy, K., “A review and recent developments in photocatalytic water-splitting using TiO2 for hydrogen production”, Renewable & Sustainable Energy Reviews, 11. 401-425. 2007.
 
21]  Rossetti, I., “Hydrogen production by photoreforming of renewable substrates”, ISRN Chemical Engineering. 1-21. 2012.
 
22]  Hasar, H., “Adsorption of nickel (II) ions from aqueous solution onto activated carbon prepared from almond husk”, Journal of Hazardous Materials, 97 (1-3). 49-57. 2003.
 
23]  Yin, S., Tan, Z., 2012. Hydrothermal liquefaction of cellulose to bio-oil under acidic, neutral and alkaline conditions, Applied Energy, 92 (C), 234-239.
 
Show Less References