World Journal of Chemical Education
ISSN (Print): 2375-1665 ISSN (Online): 2375-1657 Website: http://www.sciepub.com/journal/wjce Editor-in-chief: Prof. V. Jagannadham
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World Journal of Chemical Education. 2015, 3(4), 82-86
DOI: 10.12691/wjce-3-4-1
Open AccessArticle

Electrochromism of Methylviologen (Paraquat)

N. Aristov1 and A. Habekost1,

1Department of Chemistry, University of Education, Reuteallee 46, D-71634 Ludwigsburg, Germany

Pub. Date: July 23, 2015

Cite this paper:
N. Aristov and A. Habekost. Electrochromism of Methylviologen (Paraquat). World Journal of Chemical Education. 2015; 3(4):82-86. doi: 10.12691/wjce-3-4-1

Abstract

The herbicide paraquat, N, N’-dimethyl-4,4‘-bipyridiunium dication (N,N’-methyl viologen), is electrochromic. Experiments are described that investigate its redox chemistry (cyclic voltammetry), its optical properties (photometry and UV/Vis spectrophotometry), and its potential as a system for electrical “photoswitching” and as an accumulator for rechargeable devices. This set of teaching laboratory experiments closely reflects true procedures in commercial research and development endeavors, because the same system is probed with several quite different, but complementary, analytical methods.

Keywords:
third-year undergraduate analytical electrochemistry electrochromism hands-on learning/manipulatives

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