World Journal of Chemical Education
ISSN (Print): 2375-1665 ISSN (Online): 2375-1657 Website: http://www.sciepub.com/journal/wjce Editor-in-chief: Prof. V. Jagannadham
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World Journal of Chemical Education. 2020, 8(2), 87-91
DOI: 10.12691/wjce-8-2-4
Open AccessArticle

Undergraduate Experiment Using Absorption and Diffuse Reflectance Spectroscopies: Theoretical and Experimental Bandgap Calculations of Porphyrins and Metalloporphyrins

Muna Bufaroosha1, , Shaikha S. Al Neyadi1, Ahmed Alzamly1, Mohamad Toutounji1, Na’il Saleh1, Bashar Yousef Abuhattab1, Abdullah Al-Hemyari1, Amna Alyammahi1, Shamma Alzahmi1, Mohamed Altubji1 and Ruba Al-Ajeil1

1Department of Chemistry, UAE University, P.O. Box 15551, Al-Ain, UAE

Pub. Date: April 22, 2020

Cite this paper:
Muna Bufaroosha, Shaikha S. Al Neyadi, Ahmed Alzamly, Mohamad Toutounji, Na’il Saleh, Bashar Yousef Abuhattab, Abdullah Al-Hemyari, Amna Alyammahi, Shamma Alzahmi, Mohamed Altubji and Ruba Al-Ajeil. Undergraduate Experiment Using Absorption and Diffuse Reflectance Spectroscopies: Theoretical and Experimental Bandgap Calculations of Porphyrins and Metalloporphyrins. World Journal of Chemical Education. 2020; 8(2):87-91. doi: 10.12691/wjce-8-2-4

Abstract

In this work, an undergraduate-level experiment using 5,10,15,20-tetraphenylporphyrin (H2TPP) and its corresponding Ni(II) and Zn(II) metal complexes was developed. The bandgaps of H2TPP and its Ni(II) and Zn(II) metal complexes were calculated experimentally and theoretically to evaluate their abilities to act as light-harvesting complexes.

Keywords:
porphyrins metalloporphyrins bandgap light-harvesting complex Tauc/Davis–Mott equation diffuse reflectance spectroscopy Kubelka-Munk method

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