Journal of Polymer and Biopolymer Physics Chemistry
ISSN (Print): 2373-3403 ISSN (Online): 2373-3411 Website: Editor-in-chief: Martin Alberto Masuelli
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Journal of Polymer and Biopolymer Physics Chemistry. 2021, 9(1), 1-12
DOI: 10.12691/jpbpc-9-1-1
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Synthesis and Characterization of Polyvinyl Alkyl Ester and Polyvinyl Alcohol Homopolymers and Blends of Polyvinyl Alkyl Esters

Ronald P. D’Amelia1, and Masashi W. Kimura, Joseph Mancuso1

1Chemistry Department, Hofstra University, Hempstead, NY

Pub. Date: March 14, 2021

Cite this paper:
Ronald P. D’Amelia and Masashi W. Kimura, Joseph Mancuso. Synthesis and Characterization of Polyvinyl Alkyl Ester and Polyvinyl Alcohol Homopolymers and Blends of Polyvinyl Alkyl Esters. Journal of Polymer and Biopolymer Physics Chemistry. 2021; 9(1):1-12. doi: 10.12691/jpbpc-9-1-1


Polyvinyl alkyl esters (PVAe) are a family of macromolecules in which the ester side chains (pendant groups) increase in molar mass and hydrophobicity and decrease in structural polarity as the number of carbons in the pendant group increases. These PVAe are commonly used in adhesives, industrial coatings, plasticizers, textile finishes, chewing gum bases, and paint thickeners. The most significant polymer in the family of PVAe is polyvinyl acetate (PVAc), which is the precursor for making polyvinyl alcohol (PVOH), the largest volume water-soluble, non-toxic, biodegradable, and biocompatible polymer in the world used in the manufacture of pharmaceuticals, cosmetics, food industries, laundry detergents, and freshwater sports fishing. In this study, the goal is to synthesize polyvinyl alkyl ester homopolymers of various molecular weights by esterifying polyvinyl alcohol with alkyl anhydrides. The study also includes the synthesis of various polyvinyl alcohol homopolymers from different polyvinyl acetates via hydrolysis. These polymers were studied via gel permeation chromatography (GPC), multi-angle laser light scattering (MALLS), intrinsic viscosity, elemental analysis, Fourier-transform infrared spectroscopy (FT-IR), and nuclear magnetic resonance spectroscopy (NMR). Blends of polyvinyl alkyl ester homopolymers with defined compositions were also studied using quantitative FT-IR.

elemental analysis Fourier-transform infrared spectroscopy gel permeation chromatography homopolymers hydrolysis intrinsic viscosity multi-angle laser light scattering nuclear magnetic resonance spectroscopy polyvinyl acetate polyvinyl alkyl ester blends polyvinyl alkyl esters water-soluble polymers

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[1]  Lipsa, R. D.; Tudorachi, N.; Grigoras, A.; Vasile, C.; Gradinariu, P. Study on Poly(Vinyl Alcohol) Copolymers Biodegradation. Mem. Sci. Sect. Romanian Acad. 2015, Tome XXXVIII, 1-22.
[2]  D’Amelia, R. P.; Tomic, J. C.; Nirode, W. F. The Determination of the Solubility Parameter (δ) and the Mark-Houwink Constants (K & α) of Food Grade Polyvinyl Acetate (PVAc). J. Polym. Biopolym. Phys. Chem. 2014, 2 (4), 67-72.
[3]  Huggins, M. L. The Viscosity of Dilute Solutions of Long-Chain Molecules. IV. Dependence on Concentration. J. Am. Chem. Soc. 1942, 64 (11), 2716-2718.
[4]  Kraemer, E. O. Molecular Weights of Celluloses and Cellulose Derivates. Ind. Eng. Chem. 1938, 30 (10), 1200-1203.
[5]  Masuelli, M. A. Mark-Houwink Parameters for Aqueous-Soluble Polymers and Biopolymers at Various Temperatures. J. Polym. Biopolym. Phys. Chem. 2014, 2 (2), 37-43.
[6]  Das, N.; Chakraborty, S.; Biswas, P. K. Novel Polyvinyl Alcohol Based Cr(III)–Sn(IV) Doped In(III) Nitrate Composite Foam: Synthesis, Unit Cell Formulation and Structure. RSC Adv. 2012, 2 (24), 9183-9191.
[7]  Jipa, I.; Stoica, A.; Stroescu, M.; Dobre, L.-M.; Dobre, T.; Jinga, S.; Tardei, C. Potassium Sorbate Release from Poly(Vinyl Alcohol)-Bacterial Cellulose Films. Chem. Pap. 2012, 66 (2), 138-143.
[8]  Wei, S.; Pintus, V.; Schreiner, M. Photochemical Degradation Study of Polyvinyl Acetate Paints Used in Artworks by Py-GC/MS. J. Anal. Appl. Pyrolysis 2012, 97, 158-163.
[9]  Banfi, D.; Patiny, L. Www.Nmrdb.Org: Resurrecting and Processing NMR Spectra On-Line. Chim. Int. J. Chem. 2008, 62 (4), 280-281.
[10]  Aires-de-Sousa, J.; Hemmer, M. C.; Gasteiger, J. Prediction of 1H NMR Chemical Shifts Using Neural Networks. Anal. Chem. 2002, 74 (1), 80-90.
[11]  Castillo, A. M.; Patiny, L.; Wist, J. Fast and Accurate Algorithm for the Simulation of NMR Spectra of Large Spin Systems. J. Magn. Reson. 2011, 209 (2), 123-130.