American Journal of Environmental Protection
ISSN (Print): 2328-7241 ISSN (Online): 2328-7233 Website: Editor-in-chief: Mohsen Saeedi, Hyo Choi
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American Journal of Environmental Protection. 2013, 1(1), 1-9
DOI: 10.12691/env-1-1-1
Open AccessArticle

Surfactant Modified Zeolite from Cyclone Ash as Adsorbent for Removal of Reactive Orange 16 from Aqueous Solution

Denise A. Fungaro1, , Sueli I. Borrely1 and Terezinha E.M. Carvalho1

1Nuclear and Energy Research Institute (IPEN – CNEN/SP), São Paulo, Brazil

Pub. Date: March 02, 2013

Cite this paper:
Denise A. Fungaro, Sueli I. Borrely and Terezinha E.M. Carvalho. Surfactant Modified Zeolite from Cyclone Ash as Adsorbent for Removal of Reactive Orange 16 from Aqueous Solution. American Journal of Environmental Protection. 2013; 1(1):1-9. doi: 10.12691/env-1-1-1


Zeolite synthesized from cyclone ash (ZCA) was modified with various loadings of hexadecyltrimethylammonium bromide (HDTMA-Br) and was used as adsorbent to remove Reactive Orange 16 (RO16), an azo reactive dye, from aqueous solution. The RO16 adsorption efficiencies for ZCA and surfactant-modified zeolites from cyclone ash (SMZCAs) were compared. SMZCAs presented higher RO16 adsorption efficiency than ZCA, and SMZCA with higher loading amount of HDTMA-Br exhibited higher RO16 adsorption efficiency. A series of experiments was conducted to examine the effects of contact time, solution pH, and adsorbent dosage on dye removal. The adsorption kinetic of RO16 onto adsorbents was discussed using the pseudo-first order, pseudo-second order and intra-particle diffusion models, and the pseudo-second order model provided the best correlation of the experimental data. The equilibrium adsorption data were well represented by Langmuir isotherm model with maximum adsorption capacity of 0.58 and 12.6 mg g-1 for ZCA and SMZCA, respectively.The toxicity tests of dye solutions before and after the adsorption treatment were evaluated with D. simlis and V.ficheri.

reactive azo dye; cyclone ash zeolite cationic surfactant

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[1]  Depoi, F.S., Pozebon, D. and Kalkreuth, W.D. “Chemical characterization of feed coals and combustion-by-products from Brazilian power plants,” International Journal of Coal Geology, 76, 227-236, 2008.
[2]  Shanthakumar, S., Singh, D.N. and Phadke, R.C. “Flue gas conditioning for reducing suspended particulate matter from thermal power stations,” Progress in Energy and Combustion Science, 34, 685-695, 2008.
[3]  Silva, L.F.O. and da Boit, K.M. “Nanominerals and nanoparticles in feed coal and bottom ash: implications for human health effects,” Environmental Monitoring and Assessment, 174, 187-197, 2011.
[4]  Font, O., Córdoba, P., Leiva, C., Romeo, L.M., Bolea, I., Guedea, I., Moreno, N., Querol, X., Fernandez, C. and Díez, L.I., “Fate and abatement of mercury and other trace elements in a coal fluidised bed oxy combustion pilot plant,” Fuel, 95, 272-281, 2012.
[5]  Fungaro, D.A., Bruno, M. and Grosche, L.C. “Adsorption and kinetic studiesof methylene blue on zeolite synthesized from fly ash,” Desalination and Water Treatmen, 2, 231-239, 2009.
[6]  Fungaro, D.A., Grosche, L.C., Pinheiro, A.S., Izidoro, J.C. and Borrely, S.I. “Adsorption of methylene blue from aqueous solution on zeolitic material and the improvement as toxicity removal to living organisms,” Orbital, 2, 235-247, 2010.
[7]  Fungaro, D.A., Yamaura, M. and Carvalho, T.E.M. “Adsorption of anionic dyes from aqueous solution on zeolite from fly ash-iron oxide magnetic nanocomposite,” Journal of Atomic and Molecular Sciences, 2, 305-316, 2011.
[8]  Bowman, B.S. “Applications of surfactant-modified zeolites to environmental remediation.Review,” Microporous Mesoporous Materials, 6, 43-56, 2003.
[9]  Haggerty, G.M. and Bowman, R.S. “Sorption of chromate and other inorganic anions by organo-zeolite,” Environmental Science & Technology, 28, 452-458, 1994.
[10]  Li, Z. and Bowman, R.S. “Counterion effects on the sorption of cationic surfactant and chromate on natural clinoptilolite,” Environmental Science & Technology, 31, 2407-2412, 1997.
[11]  Fungaro, D.A. and Borrely, S.I. “Synthesis and characterization of zeolite from coal ashes modified by cationic surfactant,” Cerâmica, 58, 77-83, 2012. (in Portuguese with English abstract)
[12]  Guan, H., Bestland, E., Zhu, C., Zhu, H., Albertsdottir, D., Hutson, J., Simmons, C.T., Ginic-Markovic, M., Tao, X. and Ellis, A.V. “Variation in performance of surfactant loading and resulting nitrate removal among four selected natural zeolites,” Journal of Hazardous Materials, 183, 616-621, 2010.
[13]  Li, Z.H. “Sorption kinetics of hexadecyltrimethylammonium on natural clinoptilolite,” Langmuir, 15, 6438-6445, 1999.
[14]  Li, Z.H. and Bowman, R.S. “Sorption of perchloroethylene by surfactant-modified zeolite as controlled by surfactant loading,” Environmental Science & Technology, 32, 2278-2282, 1998.
[15]  Rozic, M., Sipusic, D.I., Sekovanic, L., Miljanic, S., Curkovic, L. and Hrenovic, J. “Sorption phenomena of modification of clinoptilolite tuffs by surfactant cations,” Journal of Colloid and Interface Science, 331, 295-301, 2009.
[16]  Mumford, J.L. and Lewtas, J. “Evaluation of fly ash collection methods for short-term bioassay studies of fluidized-bed coal combustion,” Environmental Science & Technology, 18, 765-768, 1984.
[17]  Easton, JR. The dye maker’s view. Society of Dyers and Colourists; The Alden Press, Oxford, 9-21, 1995.
[18]  Novotny, C., Dias, N., Kapanen, A., Malachova, K., Vandrovcova, M., Itavaara, M. and Lima, N.” Comparative use of bacterial, algal and protozoan tests to study toxicity of azo- and anthraquinone dyes,” Chemosphere, 63, 1436-1442, 2006.
[19]  Carvalho, T.E.M., Fungaro, D.A., Magdalena, C.P. and Cunico. P. “Adsorption of indigo carmine from aqueous solution using coal fly ash and zeolite from fly ash,” Journal of Radioanalytical and Nuclear Chemistry,289, 617-626, 2011.
[20]  Henmi, T., “Increase in cation exchange capacity of coal fly ash by alkali treatment,” Clay Science, 6, 277-282, 1987.
[21]  Blanchard, G., Maunaye, M.and Martim, G. “Removal of heavy metals from waters by means of natural zeolites,” Water Research 18, 1501-1507,1984.
[22]  Ho, Y.S. and McKay, G. “Sorption of dye from aqueous solution by peat,” Chemical Engineering Journal, 70, 115-12, 1998.
[23]  Ho, Y.S. and McKay, G. “Pseudo-second order model for sorption processes,” Process Biochemistry, 34, 451-465, 1999.
[24]  Weber, W.J. and Morris, J.C. “Kinetics of adsorption carbon from solutions,” Journal Sanitary Engeering Division Proceedings.American Society of Civil Engineers, 89, 31-60, 1963.
[25]  Ho, Y.S. “Selection of optimum sorption isotherm,” Carbon, 42, 2115-2116, 2004.
[26]  CETESB - Companhia Ambiental do Estado de São Paulo. “Água: Testes de toxicidade aguda com Daphnia similis” Claus, 1976(Cladocera, Crustácea). L5.019-1, São Paulo, 28 pp, 1986.
[27]  CETESB - Companhia Ambiental do Estado de São Paulo. “Bioensaio de toxicidade aguda com Photobacterium phosphoreum. Sistema Microtox” São Paulo, 1987.
[28]  Ghosal, S., Ebert, J.L. and Self.S.A. “Chemical composition, size distributions for fly ashes”,Fuel Processing Technology, 44, 81-94, 1995.
[29]  Pires, M. and Querol, X. “Characterization of Candiota (South Brazil) coal and combustion by-product,” International Journal of Coal Geology, 60, 57-72, 2004.
[30]  Murayama, N., Yamamoto, H., and Shibata, J. “Mechanism of zeolite synthesis from fly ash by alkali hydrothermal reaction,” International Journal of Mineral Processing, 64, 1-17, 2002.
[31]  Flues, M., Camargo, I.M.C., Figueiredo Filho, P.M., Silva, P.S.C. and Mazzilli, B.P. “Evaluation of radionucletides concentration in Brazilian Coals” Fuel, 86, 807–812, 2007.
[32]  Dong, Y, Wu, D.Y., Chen, XC and Lin, Y. “Adsorption of bisphenol A from water by surfactant-modified zeolite,” Journal of Colloid and Interface Science, 348, 585- 59, 2010.
[33]  Sheng, G., Xu, S., Boyd, S.A. “Mechanism(s) controlling sorption of neutral organic contaminants by surfactant-derived and natural organic matter,” Environmental Science & Technology, 30:1553-1557, 1996.
[34]  Custelcean, R. and Jackson, J.E. “Dihydrogen bonding: structures, energetics, and dynamics,” Chemical Reviews, 101, 1963-1980, 2001.
[35]  Stefov, V., Pejov, L. and Soptrajanov, B. “Experimental and quantum chemical study of pyrrole self-association through N–H… [π] hydrogen bonding.” Journal of MolecularStructure, 649, 231-243, 2003.
[36]  Lee, J.W., Choi, S.P., Thiruvenkatachari, R., Shim, W.G. and Moon, H. “Submerged microfiltration membrane coupled with alum coagulation/powdered activated carbon adsorption for complete decolorization of reactive dyes,” Water Reseaerch, 40, 435-444, 2006.
[37]  Calvete, T., Lima, E.C., Cardoso, N.F., Vaghetti, J.C., Dias S.L., and Pavan, F.A. “Application of carbon adsorbents prepared from Brazilian-pine fruit shell for the removal of reactive orange 16 from aqueous solution: Kinetic, equilibrium, and thermodynamic studies,” Journal of Environmental Management, 91, 1695-706, 2010.
[38]  Ramachandran, P., Vairamuthu, R., Ponnusamy, S. “Adsorption isotherms, kinetics, thermodynamics and desorption studies of reactive orange16 on activated carbon derived from Ananas comosus (L.) Carbon,” Journal of Engineering & Applied Sciences; 6, 15-26, 2011.
[39]  Won, S.W., Choi, S.B. and Yun, Y.S. “Performance and mechanism in binding of Reactive Orange 16 to various types of sludge,” Biochemical Engineering Journal, 28, 208-214, 2006.
[40]  Dias, J.M., Alvim-Ferraz, M.C.M., Almeida, M.F., Rivera-Utrilla, J. and Sanchez-Polo, M. “Waste materials for activated carbon preparation and its use in aqueous-phase treatment: a review,” Journal of Environmental Management, 85, 833-846, 2007.
[41]  Suteu, D., Malutan, T. and Bilba, D. “Agricultural waste corn cob as a sorbent for removing reactive dye orange 16: equilibrium and kinetic study,” Cellulose Chemistry and Technology, 45,413-420, 2011.
[42]  Kimura, I.Y., Laranjeira, M.C.M., Fávere, V.T. and Furlan, L. “The interaction between reactive dye containing vinylsulfone group and chitosan microspheres,” International Journal of Polymeric Materials, 51, 759-768, 2002.
[43]  Wong, S.Y., Tan, Y.P., Abdullah A.H. and Ong, S.T. “The Removal of Basic and Reactive Dyes using Quartenized Sugar Cane Bagasse,” Journal of Physical Science 20, 59-74, 2009.
[44]  Fungaro, D. A.; Yamaura, M.; Carvalho, T. E. M.; “Adsorption of anionic dyes from aqueous solution on zeolite from fly ash-iron oxide magnetic nanocomposite,” Journal of Atomic and Molecular Sciences, 2, 305-316.2011.
[45]  Ando, N., Matsui, Y., Kurotobi, Y., Nakano, Y., Matsushita, T. and Ohno, K. “Comparison of natural organic matter adsorption capacities of super-powdered activated carbon and powdered activated carbon,” Water Research, 44, 4127-4136, 2010.
[46]  Magdalena, C.P. “Adsorption of reactive remazol red RB dye of aqueous solution using zeolite of the coal ash and evaluation of acute toxicity with Daphnia similis,”
[47], 2010 (in Portuguese with English abstract).
[48]  Ferreira,C.P. “Studies on the adsorption of reactive black 5 dye of aqueous solution using zeolite of the coal ashes,
[49], 2011 (in Portuguese with English abstract).