American Journal of Environmental Protection
ISSN (Print): 2328-7241 ISSN (Online): 2328-7233 Website: Editor-in-chief: Mohsen Saeedi, Hyo Choi
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American Journal of Environmental Protection. 2014, 2(1), 16-21
DOI: 10.12691/env-2-1-4
Open AccessArticle

Synthesis and Characterization of Zeolitic Material Derived from Sugarcane Straw Ash

Denise A. Fungaro1, , Thais V. S. Reis1, Marco Antonio Logli2 and Nara A. Oliveira2

1Instituto de Pesquisas Energéticas e Nucleares, IPEN–CNEN/SP, São Paulo ,Brasil

2Centro de Pós-Graduação “Oswaldo Cruz”, São Paulo-SP– Brasil

Pub. Date: February 27, 2014

Cite this paper:
Denise A. Fungaro, Thais V. S. Reis, Marco Antonio Logli and Nara A. Oliveira. Synthesis and Characterization of Zeolitic Material Derived from Sugarcane Straw Ash. American Journal of Environmental Protection. 2014; 2(1):16-21. doi: 10.12691/env-2-1-4


Sugarcane straw ash (SCSA), an agricultural waste of sugar industry with disposal problems, was utilized as a source for the synthesis of zeolitic material. Zeolitic material was synthesized by alkali fusion followed by hydrothermal treatment. The effect of crystallization time was studied and the conditions optimized. The materials were characterized by XRD, XRF, SEM, FT-IR, Brunauer-Emmett-Teller (BET) surface area techniques, particle size analyzer, TG /DSC and nitrogen physisorption. The presence of zeolite NaP1 in adsorbent confirms successful conversion of native SCSA into zeolitic material. The physico-chemical properties of SCSA and zeolitic material were compared. The particle size distribution of zeolitic material was in the range of 0.796 – 399 µm and nitrogen adsorption indicated a surface area around 350 m2 g-1. Zeolitic material from sugarcane straw ash was examined by removal of Crystal violet from aqueous solution.

biomass ash sugarcane straw zeolite fusion method

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[1]  ÚNICA (2011) - União da Indústria de Cana-De-Açúcar. Available: [Accessed Dec.18, 2013].
[2]  Costa, S.M., Mazzola, P.G., Silva, J.C.A.R., Pahl, R, Pessoa, A. and Costa, S.A., “Use of sugarcane Straw as a source of cellulose for textile fiber production,” Industrial Crops and Products, 42. 189-194. 2013.
[3]  Saad, M.B.W., Oliveira, L.R.M., Cândido, R.G., Quintana, G., Rocha, G.J.M. and Gonçalves, A.R., “Preliminary studies on fungal treatment of sugarcane straw for organosolv pulping,” Enzyme and Microbial Technology, 43. 220-225. 2008.
[4]  Moriya, R.Y., Gonçalves, A.R. and Duarte, M.C., “Ethanol/water pulps from sugar cane straw and their biobleaching with xylanase from Bacillus pumilus,” Applied Biochemistry and Biotechnology, 137-140. 501-513. 2007.
[5]  Cançado, J.E., Saldiva, P.H., Pereira, L.A., Lara, L.B., Artaxo, P., Martinelli, L.A., Arbex, M.A., Zanobetti, A. and Braga, A.L., “The Impact of Sugar Cane–Burning Emissions on the Respiratory System of Children and the Elderly,” Environmental Health Perspectives, 114. 725-729. 2006.
[6]  Ribeiro, H., “Sugar cane burning in Brazil: respiratory health effects,” Revista de Saúde Pública, 42. 370-376. 2008.
[7]  Andrade, S.J., Cristale, J., Soares, S.F.S., Zocolo, G.J. and Marchi, M.R.R., “Contribution of sugar-cane harvesting season to atmospheric contamination by polycyclic aromatic hydrocarbons (PAHs) in Araraquara city, such showed Southeast Brazil,” Atmospheric Environment, 44. 2913-2919. 2010.
[8]  Hernandez, J.F.M, Middendorf, B., Gehrke, M. and Budelmaun, H., “Use of wastes of the sugar industry as pozzolana in lime pozzolana binders: Study of the reaction,” Cement and Concrete Research, 28. 1528-1536. 199.
[9]  Frias, M., Villar-Cociña, E. and Valencia-Morales, E., “Characterisation of sugar cane straw waste as pozzolanic material for construction: calcining temperature and kinetic parameters,” Waste Management, 27. 533-538. 2007.
[10]  Morales, E.V., Villar -Cociña, E., Frías, M., Santos, S. F. and Savastano Jr., H., “Effects of calcining conditions on the microstructure of sugar cane waste ashes (SCWA): Influence in the pozzolanic activation,” Cement and Concrete Composites, 31. 22-28. 2009.
[11]  Izidoro, J.C., Fungaro, D.A., Santos, F.S. and Wang, S., “Characteristics of Brazilian coal fly ashes and their synthesized zeolites,” Fuel Processing Technology, 97. 38-44. 2012.
[12]  Fungaro, D.A., Borrely S.I. and Carvalho, T.E.M., “Surfactant Modified Zeolite from Cyclone Ash as Adsorbent for Removal of Reactive Orange 16 from Aqueous Solution,” American Journal of Environmental Protection, 1. 1-9. 2013.
[13]  Yamaura, M. and Fungaro, D.A., “Synthesis and characterization of magnetic adsorbent prepared by magnetite nanoparticles and zeolite from coal fly ash,” Journal of Materials Science, 48. 5093-5101. 2013.
[14]  Izidoro J.C., Fungaro, D.A., Abbott, J.E. and Wang, S., “Synthesis of zeolites X and A from fly ashes for cadmium and zinc removal from aqueous solutions in single and binary ion systems,” Fuel, 103. 827-834. 2013.
[15]  Shah, B., Tailor, R.and Shah, A., “Adaptation of bagasse fly ash, a sugar industry solid waste into zeolitic material for the uptake of phenol,” Environmental Progress & Sustainable Energy, 30. 358-367, 2011.
[16]  Shah, B., Tailor, R. and Shah, A., “Sorptive sequestration of 2- chlorophenol by zeolitic materials derived from bagasse fly ash,” Journal of Chemical Technology and Biotechnology, 86. 1265-1275. 2011.
[17]  Shah, B., Tailor, R. and Shah, A., “Zeolitic bagasse fly ash as a low-cost sorbent for the sequestration of p-nitrophenol: equilibrium, kinetics, and column studies,” Environmental Science and Pollution Research International, 19. 1171-86. 2012.
[18]  Worathanakul, P., Kittipalarak, S. and Anusarn, K., “Utilization Biomass from Bagasse Ash for Phillipsite Zeolite Synthesis,” Advanced Materials Research, 383-390. 4038-4042. 2011.
[19]  Kruk, M., Jaroniec, M. and Sayari, A, “Application of large pore MCM-41 molecular sieves to improve pore size analysis using nitrogen adsorption measurements,” Langmuir, 13. 6267-6273. 1997.
[20]  Barboza Filho, M.P. and Prabhu, A.S., Aplicação de silicato de cálcio na cultura do arroz (Application of calcium silicate in rice culture) - Circular Técnica 51, EMBRAPA. Santo Antônio de Goiás, 2002. (in portuguese).
[21]  Murayama, N., Yamamoto, H. and Shibata, “Mechanism of zeolite synthesis from coal fly ash by alkali hydrothermal reaction,” International Journal of Mineral Processing, 64. 1-17. 2002.
[22]  Derkowski, A. and Michalik, M., “Statistical approach to the transformation of fly ash into zeolites,” Mineralogia Polonica, 38. 47-69. 2007.
[23]  Moutsatsou, A., Stamatakis, E., Hatzitzotzia, K. and Protontarios, V., “The utilization of Ca-rich and Ca-Si-rich fly ashes in zeolites production,” Fuel, 85: 657-663, 2006.
[24]  Mouhtaris, T., Charistos, D., Kantiranis, N., Filippidis, A., KassoliFournaraki, A. and Tsirambidis, A., “GIS-type zeolite synthesis from Greek lignite sulphocalcic fly ashes promoted by NaOH solutions,” Microporous and Mesoporous Material, 61, 57-67. 2003.
[25]  Vadapalli, V.R.K., Gitari, W.M., Ellendt, A., Petrik, L.F. and Balfour, G., “Synthesis of zeolite-p from coal fly ash derivative and its utilisation in mine-water remediation,” South African Journal of Science, 106. 1-7. 2010.
[26]  Atun, G., Hisarliet, G., Kurtoglu, A.E. and Ayar, N., “A comparison of basic dye adsorption onto zeolitic materials synthesized from fly ash,” Journal of Hazardous Materials, 187. 562-573. 2011.
[27]  Figueiredo, J.L. and Ramôa Ribeiro, F., Catálise Heterogênea. Fundação Calouste Gulbenkian, Lisboa, 1989.