N,N’-Diphenyldecanediamide: A Fluoride Ion Sensitive and Selective Amide

Meenakshi Thakran¹, Anek pal Gupta¹ and Neeru Dabas^1,

¹Amity School of Applied Sciences, Amity University Haryana, Panchgaon, Manesar, Gurgaon, Haryana, India

Cite this paper:
Meenakshi Thakran, Anek pal Gupta and Neeru Dabas. N,N’-Diphenyldecanediamide: A Fluoride Ion Sensitive and Selective Amide. American Journal of Sensor Technology. 2017; 4(1):1-9. doi: 10.12691/ajst-4-1-1

Abstract

A fluoride ion (F^-) sensitive organic ligand N, N’-Diphenyldecanediamide (L1), has been synthesized by the reaction of sebacoyl chloride with aniline in presence of triethylamine at room temperature. Spectroscopic investigation revealed F^- interacts strongly with L1 in comparison to other competitive anions (Cl^-, Br^- and NO₃^-) and as a consequence induces deprotonation in the NH fragment of L1. Different spectroscopic techniques such as ¹H NMR, UV-Vis and fluorescence emission spectroscopy supports the fast and distinct response behavior of N, N’-substituted polymethylene diamide towards F^-.

Keywords:
fluoride responsive selective flexible polymethylene diamide

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