American Journal of Nanomaterials
ISSN (Print): 2372-3114 ISSN (Online): 2372-3122 Website: http://www.sciepub.com/journal/ajn Editor-in-chief: Apply for this position
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American Journal of Nanomaterials. 2016, 4(1), 8-11
DOI: 10.12691/ajn-4-1-2
Open AccessArticle

Microwave Assisted Synthesis of Sn Promoted Pt Catalysts and Their Ethanol Electro-oxidation Activities

Dilan Atbas1, Aykut Çağlar1, Hilal Kivrak1, and Arif Kivrak2

1Chemical Engineering Department, Yüzüncü Yıl University, Van, Turkey

2Department of Chemistry, Yüzüncü Yıl University, Van, Turkey

Pub. Date: May 21, 2016

Cite this paper:
Dilan Atbas, Aykut Çağlar, Hilal Kivrak and Arif Kivrak. Microwave Assisted Synthesis of Sn Promoted Pt Catalysts and Their Ethanol Electro-oxidation Activities. American Journal of Nanomaterials. 2016; 4(1):8-11. doi: 10.12691/ajn-4-1-2

Abstract

In the present work, bi-metallic Pt-Sn electro catalysts were prepared by microwave assisted polyol method at 9:1, 7:3, and 5:5 Pt: Sn atomic ratios on carbon nanotube. The ethanol electro-oxidation activities of these catalysts were measured by cyclic voltammetry (CV). The effect of Sn addition to Pt for the improvement of ethanol electro-oxidation was also measured by CV measurements. Pt-Sn (07:03) catalyst exhibits the highest ethanol electro-oxidation activity. Furthermore, the rotating disk measurements were performed at 0-2000 rpm rotating rates on Pt-Sn (07:03) catalyst. The effect of ethanol concentration on ethanol electro-oxidation activity at varying ethanol concentrations (0.03 M-8.00 M) were measured on Pt-Sn (07:03) catalyst. CO stripping measurements were performed to determine the CO resistance of Pt-Sn electrocatalysts. As a result, CO oxidation onset potential decreases by the addition of Sn to Pt, revealing that Sn addition promotes the CO resistance of platinum.

Keywords:
ethanol electro-oxidation microwave assisted polyol method DEFCs Pt:Sn catalysts cyclic voltammetry

Creative CommonsThis work is licensed under a Creative Commons Attribution 4.0 International License. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/

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